[(1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene)GaH3] | 1187968-84-8

• 英文名称: [(1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene)GaH3]
• CAS: 1187968-84-8
• 化学式: C₁₉H₂₃GaN₂
• 分子量: 349.128
• InChiKey: XJYZQDFRSZCYOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  lithium tetrahydridogallate 、 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene 以 乙醚 为溶剂， 以72%的产率得到[(1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene)GaH3]
  参考文献：
  名称：

  N-heterocyclic carbene coordinated gallanes and chlorogallanes

  摘要：

  The preparation of the N-heterocyclic carbene coordinated gallium complexes [GaH3(IXy)] (1), [GaH3(IDipp)] (2), [GaClH2(IMes)] (3) and [GaCl2H(IMes)] (4), where IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene, IDipp = 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene and IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, are reported. All four complexes have been characterised by H-1, C-13 NMR and IR spectroscopy and, for complexes 2, 3 and 4, single crystal X-ray structure determination. These compounds represent some of the most thermally stable molecular gallium hydrides known, with 4 being the most thermally stable gallium hydride reported (dec. 274 degrees C). These remarkable thermal stabilities translate to significant aerobic stability such that all four compounds may be handled in dry air without significant decomposition. Compounds 2, 3 and 4 exist as distorted tetrahedra in the solid state with gallium to carbene C-donor bonds that shorten with increasing Lewis acidity of the gallium centre. Compound 2 co-crystallizes with 1 equiv. of 2,6-diisopropylphenylaniline and exhibits several weak intermolecular bonding interactions in the solid-state. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.030