A new synthesis of allylic alcohols or their derivatives via reductive elimination from γ-phenylthio-β-nitroalcohols with tributyltinhydride
作者:Noboru Ono、Akio Kamimura、Aritsune Kaji
DOI:10.1016/s0040-4039(01)81593-8
日期:——
Allylic alcohols are readily prepared by the Bu3SnH-promoted elimination reaction from γ-phenylthio-β-nitroalcohls which are obtained by the joint reaction of nitroolefins, thiophenol, and aldehydes.
烯丙醇易于通过Bu 3 SnH促进的消除反应,由γ-
苯硫基-β-硝基醇通过硝基
烯烃,
硫酚和醛的联合反应制得。