4-methoxymethyl-2,3,5,6-tetrafluorobenzyl 1R-trans-3-(2-cyano-1-propenyl(Z))-2,2-dimethylcyclopropanecarboxylate | 1246640-77-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl 1R-trans-3-(2-cyano-1-propenyl(Z))-2,2-dimethylcyclopropanecarboxylate
• 英文别名: 2,3,5,6-tetrafluoro-4-methoxymethyl-benzyl (1R,3R)-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylate；(2,3,5,6-tetrafluoro-4-methoxymethylbenzyl) (E)-(1R,3R)-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylate；2,3,5,6-Tetrafluoro-4-(methoxymethyl)benzyl (E)-(1R,3R)-3-(2-cyanoprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate；[2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl (1R,3R)-3-[(E)-2-cyanoprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate
• CAS: 1246640-77-6
• 化学式: C₁₉H₁₉F₄NO₃
• 分子量: 385.358
• InChiKey: DPJITPZADZSLBP-PIPQINALSA-N

物化性质

• 沸点：
  403.0±45.0 °C(Predicted)
• 密度：
  1.321±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  59.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl (1R,3R)-3-(1-acetyloxy-2-cyanoprop-2-enyl)-2,2-dimethylcyclopropane-1-carboxylate 在 sodium tetrahydroborate 、 盐酸 、 水 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以77.8%的产率得到
  参考文献：
  名称：

  EP2241551

  摘要：

  公开号：

文献信息

• Process for Producing 3-(2-Cyano-1-propenyl)-2,2- Dimethylcyclopropanecarboxylic Acid or Salt Thereof
  申请人：Uekawa Toru

  公开号：US20120016150A1

  公开（公告）日：2012-01-19

  A process for producing comprising reacting a 3-formyl-2,2-dimethylcyclopropanecarboxylate and propionitrile in the presence of a base to obtain 3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid or its salt.

  生产过程包括在碱的存在下，通过将3-甲酰基-2,2-二甲基环丙基羧酸酯和丙腈反应，得到3-(2-氰丙烯基)-2,2-二甲基环丙基羧酸或其盐。
• METHOD FOR PRODUCING CYCLOPROPANECARBOXYLIC ACID ESTER
  申请人：Ohshita Jun

  公开号：US20120029227A1

  公开（公告）日：2012-02-02

  A method for producing a cyclopropanecarboxylate represented by formula (III): wherein, R represents a chain hydrocarbon group having 1 to 10 carbon atoms optionally having at least one member selected from the group consisting of halogen atoms, acyl groups having 2 to 7 carbon atoms optionally having a substituent, alkoxy groups having 1 to 7 carbon atoms optionally having a substituent, alkylthio groups having 1 to 3 carbon atoms and phenyl groups optionally having a substituent, a cyclic hydrocarbon group having 3 to 10 carbon atoms or a hydrogen atom; comprising reacting a cyclopropanecarboxylate represented by formula (I): wherein, R represents the same meaning as described above; and 2-cyanopropionic acid in the presence of a base.

  一种制备式（III）的环丙烷羧酸酯的方法：其中，R代表具有1至10个碳原子的链烃基，可选地具有来自卤素原子、具有2至7个碳原子的酰基、具有取代基的1至7个碳原子的烷氧基、具有1至3个碳原子的烷基硫基和可选地具有取代基的苯基、具有3至10个碳原子的环烃基或氢原子中至少一种的成员的群；包括在碱存在下将式（I）所表示的环丙烷羧酸酯与2-氰基丙酸反应。
• Ester Compound and Use Thereof
  申请人：Mori Tatsuya

  公开号：US20100035985A1

  公开（公告）日：2010-02-11

  An ester compound represented by the formula (1): wherein R represents a C1-C4 alkyl group or a C3-C4 alkenyl group, and A represents a single bond or an oxygen atom, has an excellent pest controlling efficacy, and it is useful as an active ingredient of a pest controlling agent.

  化学式为（1）的酯类化合物：其中R代表C1-C4烷基或C3-C4烯基，A代表单键或氧原子，具有卓越的杀虫效果，是一种杀虫剂的有效成分。
• PESTICIDAL COMPOSITION AND METHOD FOR CONTROLLING A PEST
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2139340B1

  公开（公告）日：2013-04-10
• METHOD FOR PRODUCING CYCLOPROPANE CARBOXYLIC ACID COMPOUND AND INTERMEDIATE THEREFOR
  申请人：Uekawa Toru

  公开号：US20100280267A1

  公开（公告）日：2010-11-04

  A method for producing a cyclopropanecarboxylic acid compound represented by formula (VI) (wherein R denotes the same as below), which comprising reacting a compound represented by formula (V) (wherein R denotes a chain hydrocarbon group having 1 to 10 carbon atoms or the like, and R 1 denotes a chain hydrocarbon group having 1 to 10 carbon atoms optionally substituted with a halogen atom or the like) with an alkali metal borohydride compound in the presence of a solvent.