3,3-双(5,6-二苯基-1,2,4-三嗪) | 93372-16-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 3,3-双(5,6-二苯基-1,2,4-三嗪)
• 英文名称: 3,3'-Bi-1,2,4-triazin, 5,5',6,6'-tetraphenyl
• 英文别名: 5,5',6,6'-tetraphenyl-3,3'-bi-1,2,4-triazine；3,3'-Bis(5,6-diphenyl-1,2,4-triazin)；3,3'-bis(5,6-diphenyl)-1,2,4-triazine；bis-(5,6-diphenyl-[1,2,4]-triazinyl)pyridine；5,6,5',6'-tetraphenyl-[3,3']bi[1,2,4]triazinyl；btb；3-(5,6-diphenyl-1,2,4-triazin-3-yl)-5,6-diphenyl-1,2,4-triazine
• CAS: 93372-16-8
• 化学式: C₃₀H₂₀N₆
• 分子量: 464.529
• InChiKey: QQFAPSRWCWFNGN-UHFFFAOYSA-N

物化性质

• 熔点：
  219-222 °C
• 沸点：
  693.1±65.0 °C(Predicted)
• 密度：
  1.238±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  36
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  3,3-双(5,6-二苯基-1,2,4-三嗪) 在 氯磺酸 作用下， 反应 3.0h， 以95%的产率得到3,3’,3’’,3’’’-[3,3’-bi-1,2,4-triazine-5,5’,6,6’-tetrayl]tetrabenzenesulfonyl chloride
  参考文献：
  名称：

  Efficient masking of corrosion and fission products such as Ni(ii) and Pd(ii) in the presence of the minor actinide Am(iii) using hydrophilic anionic or cationic bis-triazines

  摘要：

  我们报道了首批亲水性的3,3'-双(1,2,4-三嗪)配体，并将其应用作掩蔽剂，以抑制用于核燃料溶液中发现的腐蚀和裂变产物的提取。

  DOI：

  10.1039/c5cc02336j
• 作为产物：
  描述：

  乙烷二肼基n酰胺 、 联苯甲酰 在 三乙胺 作用下， 以 1,4-二氧六环 为溶剂， 反应 48.0h， 以77%的产率得到3,3-双(5,6-二苯基-1,2,4-三嗪)
  参考文献：
  名称：

  Efficient masking of corrosion and fission products such as Ni(ii) and Pd(ii) in the presence of the minor actinide Am(iii) using hydrophilic anionic or cationic bis-triazines

  摘要：

  我们报道了首批亲水性的3,3'-双(1,2,4-三嗪)配体，并将其应用作掩蔽剂，以抑制用于核燃料溶液中发现的腐蚀和裂变产物的提取。

  DOI：

  10.1039/c5cc02336j

文献信息

• Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1′-Bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP)
  作者：Sayak Roy、Travis Blane、Alyssia Lilio、Clifford P. Kubiak

  DOI：10.1016/j.ica.2011.02.005

  日期：2011.8

  Organometallic complexes of Re(I) with ligands having opposite redox properties have been synthesized and structurally characterized. X-ray crystal structures of the complexes show typical fac-Re-I(CO)(3) coordination to the redox active ligands. Complete electrochemical and spectroelectrochemical studies on the ligands and the metal complexes were performed. The IR-spectroelectrochemical responses were monitored using the fac-Re(CO)(3) unit as a probe. The 15-20 cm(-1) hypsochromic or bathochromic shift of the nu(CO) bands upon reduction or oxidation is attributed to ligand-centered processes. (C) 2011 Elsevier B.V. All rights reserved.
• Chirale Erkennung bei Trisdiimin -Metallkomplexen: 1. Strukturen von Tris-(3,3?-bi-1,2,4-triazin)eisen(II)-Komplexen
  作者：J. Breu、K. -J. Range、E. Herdtweck

  DOI：10.1007/bf00818160

  日期：1994.2

  By cyclo-condensation of beta-diketones with oxamiddihydrazone 3,3'-bi-triazines with different substituents in 5,5'-, 6,6'-position and their corresponding iron(II)-trischelates were synthesized. The structures of the complexes tris-(3,3'-bi-1,2,4-triazine, 5,5',6,6'-tetramethyl)iron(II) ditetrachloroferrate(III) and tris-(3,3'-bi-1,2,4-triazine, 5,5',6,6'-tetraphenyl)iron(II) ditetrachloroferrate(III) could be solved by means of single crystal X-ray-analysis. Both complexes crystallize from racemic solutions in an enantiomorphic space group (P2(1)3 and P2(1)2(1)2, respectively) with one molecule in the asymmetric unit, i.e. the rare phenomenon of spontaneous resolution by crystallization is observed. Hence, homochiral intermolecular interactions are strongly preferred over heterochiral ones.
• Temperature dependence of dual emission in ruthenium(II) complexes containing 3,3′-bi-1,2,4-triazine derivatives
  作者：Yu Chen、Xu Zhou、Xu-Hui Wei、Bo-Le Yu、Hui Chao、Liang-Nian Ji

  DOI：10.1016/j.inoche.2010.05.019

  日期：2010.9

  Three new ruthenium(II) polypyridyl complexes with highly pi-deficient ligands, [Ru(bpy)(2)(btm)](2+) (1), [Ru (bpy)(2)(btb)](2+) (2) and [Ru(bpy)(2)(btp)](2+) (3) (bpy = 2,2'-bipyridine, btm = 3,3'-bis(5,6-dimethyl-1,2,4-triazine, btb= 3,3'-bis(5,6-diphenyl-1,2,4-triazine, btp = 3,3'-bis(phenanthro[9,10-e][1,2,4]triazine) were synthesized and characterized. Electrochemical data together with molecular calculations show that the first redox process in these complexes is not bpy based. Complexes 1, 2 and 3 display luminescence in ethanol/methanol (4/1, V/V) at 80K, and all three complexes exhibit a temperature switch from single (150 K) to dual (80 K) emission behavior. (C) 2010 Elsevier B.V. All rights reserved.
• Dedichen, 1936, # 5, p. 28
  作者：Dedichen

  DOI：——

  日期：——