cis-3-methyl-Δ⁴-tetrahydrophthalic anhydride | 5333-84-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异苯并呋喃
• 英文名称: cis-3-methyl-Δ⁴-tetrahydrophthalic anhydride
• 英文别名: (3aS,7aR)-4-methyl-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione
• CAS: 5333-84-6；35438-81-4；35438-82-5；35438-83-6；35438-84-7；38360-97-3；51268-24-7；51268-25-8；51268-26-9；51348-45-9；55449-34-8
• 化学式: C₉H₁₀O₃
• 分子量: 166.177
• InChiKey: XPEKVUUBSDFMDR-FWPZAIACSA-N

物化性质

• 熔点：
  40-41 °C
• 沸点：
  122-134 °C(Press: 4 Torr)
• 密度：
  1.204±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2932999099
• 包装等级：
  III
• 危险类别：
  6.1
• 危险性防范说明：
  P261,P264,P272,P280,P284,P302+P352+P333+P313+P363,P304+P340+P342+P311,P305+P351+P338+P337+P313,P501
• 危险品运输编号：
  2811
• 危险性描述：
  H315,H317,H319,H334

反应信息

• 作为反应物：
  描述：

  20,24-diamino-2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene 、 cis-3-methyl-Δ⁴-tetrahydrophthalic anhydride 在 PPA 作用下， 反应 2.0h， 以78%的产率得到14,36-dimethyl-2,5,8,24,27,30-hexaoxa-20,42-diazaheptacyclo[29.13.0.09,23.011,21.013,18.033,43.035,40]tetratetraconta-1(31),9(23),10,15,21,32,37,43-octaene-12,19,34,41-tetrone
  参考文献：
  名称：

  Ivanov, E. I.; Polishchuk, A. A.; Terent'ev, P. B., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 1.2, p. 122 - 124

  摘要：

  DOI：
• 作为产物：
  描述：

  马来酸酐 、 反-1,3-戊二烯 以 丙酮 为溶剂， 反应 9.0h， 以88%的产率得到cis-3-methyl-Δ⁴-tetrahydrophthalic anhydride
  参考文献：
  名称：

  Augé, Jacques; Gil, Richard; Kalsey, Sophie, Synlett, 2000, # 6, p. 877 - 879

  摘要：

  DOI：

文献信息

• Resin composition
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：EP0340019A2

  公开（公告）日：1989-11-02

  A resin composition comprising (a) 40 to 80% by weight of a resin comprising an oligomer having a number average molecular weight of 900 to 3,000 in terms of polystyrene equivalent obtained by gel permeation chromatography and having two or more terminal (meth)acrylate groups and an unsaturated polyester, and (b) 20 to 60% by weight of methyl (meth)acrylate monomer.

  一种树脂组合物，包括 (a) 40%至 80%（重量百分比）的树脂，该树脂包括 通过凝胶渗透色谱法获得的平均分子量为 900 至 3 000（以聚苯乙烯当量计）的低聚物，该低聚物具有两个或多个末端（甲基）丙烯酸酯基团和 不饱和聚酯，以及 (b) 20%至 60%（按重量计）的(甲基)丙烯酸甲酯单体。
• CROSSLINKABLE AROMATIC RESINS HAVING PROTONIC ACID GROUPS AND ION CONDUCTIVE POLYMER MEMBRANES BINDERS AND FUEL CELLS MADE BY USING THE SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1457511A1

  公开（公告）日：2004-09-15

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由直接键合在芳香环上的 C1 至 C10 烷基和羰基或碳碳双键或三键组成。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂，是优选的。
• Crosslinkable aromatic resin having protonic acid group, and ion conductive polymer membrane, binder and fuel cell using the resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20040191602A1

  公开（公告）日：2004-09-30

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C 1 to C 10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由 C 1 至 C 10 烷基和/或主链上有 1 至 3 个碳原子的亚烷基，其中至少有一个直接与芳香环键合的碳原子与氢、羰基或碳碳双键或三键键合。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂是首选。
• Sibarov, D. A.; Dokuchaeva, T. G.; Lezdin, S. Yu., Journal of applied chemistry of the USSR, 1988, vol. 61, # 9, p. 1863 - 1866
  作者：Sibarov, D. A.、Dokuchaeva, T. G.、Lezdin, S. Yu.、Silin, A. A.

  DOI：——

  日期：——
• US7345135B2
  申请人：——

  公开号：US7345135B2

  公开（公告）日：2008-03-18