[9-(10-phenylanthryl)](4-bromo-2,6-dimethylphenyl)diazomethane | 677351-12-1

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: [9-(10-phenylanthryl)](4-bromo-2,6-dimethylphenyl)diazomethane
• 英文别名: 9-[(4-Bromo-2,6-dimethylphenyl)-diazomethyl]-10-phenylanthracene
• CAS: 677351-12-1
• 化学式: C₂₉H₂₁BrN₂
• 分子量: 477.403
• InChiKey: OUHXRCGHFYBNCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [9-(10-phenylanthryl)](4-bromo-2,6-dimethylphenyl)diazomethane 在 bis-triphenylphosphine-palladium(II) chloride 、 sodium hydroxide 、 copper(l) iodide 、 三乙胺 、 叔丁醇 作用下， 生成 9-[Diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenylanthracene
  参考文献：
  名称：

  Quintet Bis(carbene) from Triplet Diarylcarbenes Introduced at the 1,8-Position of Anthracene

  摘要：

  [9-{10-Phenyl}anthryl](4-bromo-2,6-dimethylphenyl)diazomethane was found to be stable enough to survive Sonogashira coupling reaction conditions and was converted to [9-{10-phenyl}anthryl](4-trimethylsilyiethynyl-2,6-dimethylphenyl)diazomethane, which was reacted with 1,8-dliodoanthracene to give bis(diazo) compound. Bis(carbene) generated by irradiation of the bis(diazo) compound generated a fairly persistent S = 2 quintet state.

  DOI：

  10.1021/ol049877j
• 作为产物：
  描述：

  [9-(10-phenylanthryl)](4-bromo-2,6-dimethylphenyl)chloromethane 在 silver tetrafluoroborate 、 氯甲烷 、 potassium tert-butylate 、 sodium acetate 、 dinitrogen tetraoxide 作用下， 以 四氢呋喃 、 四氯化碳 、 二氯甲烷 为溶剂， 生成 [9-(10-phenylanthryl)](4-bromo-2,6-dimethylphenyl)diazomethane
  参考文献：
  名称：

  Quintet Bis(carbene) from Triplet Diarylcarbenes Introduced at the 1,8-Position of Anthracene

  摘要：

  [9-{10-Phenyl}anthryl](4-bromo-2,6-dimethylphenyl)diazomethane was found to be stable enough to survive Sonogashira coupling reaction conditions and was converted to [9-{10-phenyl}anthryl](4-trimethylsilyiethynyl-2,6-dimethylphenyl)diazomethane, which was reacted with 1,8-dliodoanthracene to give bis(diazo) compound. Bis(carbene) generated by irradiation of the bis(diazo) compound generated a fairly persistent S = 2 quintet state.

  DOI：

  10.1021/ol049877j