| 1415025-17-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1415025-17-0
• 化学式: C₆₄H₉N
• 分子量: 791.782
• InChiKey: RVQYMAQVBHRSEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.32
• 重原子数：
  65.0
• 可旋转键数：
  3.0
• 环数：
  33.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  3.01
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  在 三氟甲磺酸 作用下， 以 邻二氯苯 为溶剂， 反应 0.1h， 生成
  参考文献：
  名称：

  Facile and Exclusive Formation of Aziridinofullerenes by Acid-catalyzed Denitrogenation of Triazolinofullerenes

  摘要：

  Variously substituted [6,6]closed aziridinofullerenes were exclusively obtained from acid-catalyzed denitrogenation of triazolinofullerenes without formation of relevant [5,6]open azafulleroids, which are the major products on noncatalyzed denitrogenation. The mechanistic consideration by DFT calculations suggested a reaction sequence involving initial pre-equilibrium protonation of the triazoline N-1 atom, generation of aminofullerenyl cation by nitrogen-extrusion, and final aziridination.

  DOI：

  10.1021/ol302928d

文献信息

• Cu(OAc)₂-promoted reaction of [60]fullerene with primary amines or diamines
  作者：Xin-Wei Lu、Meng-Lei Xing、Chun-Bao Miao、Jia-Xing Li、Xiao-Qiang Sun、Hai-Tao Yang

  DOI：10.1039/c5ob01048a

  日期：——

  The Cu(OAc)₂-mediated oxidative dehydrogenative addition of easily available primary amines to C₆₀ allows the concise preparation of aziridinofullerenes. Moreover, the Cu(OAc)₂-promoted reaction of C₆₀ with diamines affords C₆₀-fused cyclic 1,2-diaminated fullerenes.

  Cu(OAc)2介导的氧化脱氢加成反应可以将易得的一级胺加成到C60上，从而简洁地制备出环氧丙烷基富勒烯。此外，Cu(OAc)2促进的C60与二元胺的反应可以得到C60融合的环状1,2-二胺基富勒烯。
• Hypervalent Iodine Reagent Mediated Reaction of [60]Fullerene with Amines
  作者：Chun-Bao Miao、Xin-Wei Lu、Ping Wu、Jiaxing Li、Wen-Long Ren、Meng-Lei Xing、Xiao-Qiang Sun、Hai-Tao Yang

  DOI：10.1021/jo402079m

  日期：2013.12.6

  The hypervalent iodine reagent mediated reaction of C-60 with various readily available amines for the easy preparation of iminofullerenes has been developed. The reaction between C-60 and sulfonamides can be effectively controlled to selectively synthesize azafulleroids or aziridinofullerenes under PhI(OAc)(2)/I-2 or PhIO/I-2/CuCl/lutidine conditions, respectively. For phosphamide and urea, only one isomer is obtained. However, carbamate gives three kinds of products. Interestingly, the reaction of C-60 with alkylamines allows the effective synthesis of aziridinofullerenes and regioselective cis-1-bisaziridinofullerenes.
• Cycloaddition of alkyl azides to fullerene C60 in the presence of Cu(OTf)2
  作者：Arslan R. Akhmetov、Airat R. Tuktarov、Natal’ya R. Popod’ko、Usein M. Dzhemilev

  DOI：10.1016/j.mencom.2015.09.009

  日期：2015.9

  Cycloaddition of linear and cyclic alkyl azides to fullerene C-60 in the presence of stoichiometric amounts of copper triflate affords N-(cyclo)alkylaziridinofullerenes.