Zn(II)-5,15-bis(4-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin | 1252590-46-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(II)-5,15-bis(4-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin
• CAS: 1252590-46-7
• 化学式: C₅₈H₅₀N₆O₈Zn
• 分子量: 1024.46
• InChiKey: VOVCVGDUEXHRCQ-BVPXHABYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  3,4-二氢-2H-吡喃 、 Zn(II)-5,15-bis(4-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin 在 对甲苯磺酸 作用下， 以 二氯甲烷 为溶剂， 反应 3.17h， 以56.5%的产率得到Zn(II)-5,15-bis(4-(2-(2-(2-(tetrahydro-2H-pyran-2-yloxy)ethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin
  参考文献：
  名称：

  Boronic Acid Porphyrin Receptor for Ginsenoside Sensing

  摘要：

  Ginsenoside detection was pursued through the design of a porphyrin receptor containing two boronic acid units. This receptor was found to undergo different degrees of fluorescence quenching with five ginsenoside guests and an acylated derivative. The trends in the 1:1 binding constants, as well as ESI-HRMS analysis, support a binding mode in which the ginsenoside sugar units are bound to the boronic acid groups, while the steroid core and porphyrin ring participate in hydrophobic interactions.

  DOI：

  10.1021/ol1019647
• 作为产物：
  描述：

  Zn(II)-5,15-bis(4-hydroxyphenyl)-10,20-bis(4-cyanophenyl)porphyrin 、 三乙二醇单对甲苯磺酸酯 在 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 26.0h， 以57.5%的产率得到Zn(II)-5,15-bis(4-(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)phenyl)-10,20-bis(4-cyanophenyl)porphyrin
  参考文献：
  名称：

  Boronic Acid Porphyrin Receptor for Ginsenoside Sensing

  摘要：

  Ginsenoside detection was pursued through the design of a porphyrin receptor containing two boronic acid units. This receptor was found to undergo different degrees of fluorescence quenching with five ginsenoside guests and an acylated derivative. The trends in the 1:1 binding constants, as well as ESI-HRMS analysis, support a binding mode in which the ginsenoside sugar units are bound to the boronic acid groups, while the steroid core and porphyrin ring participate in hydrophobic interactions.

  DOI：

  10.1021/ol1019647