[Cd-tris(ethylenediamine)](ClO4)3 | 100515-34-2

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [Cd-tris(ethylenediamine)](ClO4)3
• CAS: 100515-34-2
• 化学式: C₆H₂₄CdN₆*2ClO₄
• 分子量: 491.608
• InChiKey: NOYAEXLVCFDTIA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cadmium(II) perchlorate hexahydrate 、 乙二胺 以 水 为溶剂， 生成 [Cd-tris(ethylenediamine)](ClO4)3
  参考文献：
  名称：

  Cd(II)–ethylenediamine mono- and bimetallic complexes – Synthesis and characterization by 113Cd NMR spectroscopy and single crystal X-ray diffraction

  摘要：

  Formation of three Cd(II)-ethylenediamine (en) complexes ([Cd(en)(n)](2+), n = 1-3) in aqueous solution and in DMSO solvent has been established by means of Cd-113 NMR spectroscopy. It is clearly shown that Cd(II)-en complexes form primarily in basic solutions. A correlation between the Cd-113 NMR chemical shifts and the ethylenediamine (en) coordination number has been observed and discussed. Two single crystals with the composition [Cd-2(en)(5)](ClO4)(4) (1) and [Cd(en)(3)](ClO4)(2) (2) were prepared from aqueous solution, and their structures were determined by single crystal X-ray diffraction. Cd(II) ions are coordinated by six atoms in both compounds, I and 2: via five N-donor atoms and one O-donor atom forming a bimetallic complex 1, and via six N-donor atoms forming a distorted octahedral monometallic complex 2. Raman spectra of complexes 1 and 2 also provide additional evidence that the cis-form of the bridging en is present in complex 1. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.04.029