[(benzyl)3tin(IV)(furfuraldehyde semicarbazone(-H))] | 1290545-14-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(benzyl)3tin(IV)(furfuraldehyde semicarbazone(-H))]
• CAS: 1290545-14-0
• 化学式: C₂₇H₂₇N₃O₂Sn
• 分子量: 544.24
• InChiKey: LCGSGCHNGGYPSB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(benzyl)3tin(IV)(furfuraldehyde semicarbazone(-H))] 以 neat (no solvent) 为溶剂， 生成 tin(II) oxide
  参考文献：
  名称：

  Preparation of Tin Chalcogenide Nanoparticles Using Tribenzyltin(IV) Semi- and Thiosemicarbazone Precursors

  摘要：

  The reactions of tribenzyltin(IV)chloride with one mole equivalent of sodium salts of semi- and thiosemicarbazone ligands gave complexes of the type Bz3SnL (L = semicarbazone or thiosemicarbazone moiety). These compounds have been characterized by elemental analysis, IR, 1H, 13C{1H}, and 119Sn (in few cases), NMR spectroscopy, and thermogravimetric analysis. Thermal decomposition of complexes was carried out. The materials obtained were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray analysis, absorption, and fluorescence spectroscopy. The XRD showed formation of SnS and SnO from thiosemicarbazone and semicarbazone complexes, respectively. The TEM images showed presence of nearly spherical particles.

  DOI：

  10.1080/15533174.2010.522674
• 作为产物：
  描述：

  三苄基氯化锡 、 (呋喃-2-基亚甲基氨基)脲 在 NaH 、 isopropanol 作用下， 以 四氢呋喃 、 异丙醇 为溶剂， 以46.13%的产率得到[(benzyl)3tin(IV)(furfuraldehyde semicarbazone(-H))]
  参考文献：
  名称：

  Preparation of Tin Chalcogenide Nanoparticles Using Tribenzyltin(IV) Semi- and Thiosemicarbazone Precursors

  摘要：

  The reactions of tribenzyltin(IV)chloride with one mole equivalent of sodium salts of semi- and thiosemicarbazone ligands gave complexes of the type Bz3SnL (L = semicarbazone or thiosemicarbazone moiety). These compounds have been characterized by elemental analysis, IR, 1H, 13C{1H}, and 119Sn (in few cases), NMR spectroscopy, and thermogravimetric analysis. Thermal decomposition of complexes was carried out. The materials obtained were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray analysis, absorption, and fluorescence spectroscopy. The XRD showed formation of SnS and SnO from thiosemicarbazone and semicarbazone complexes, respectively. The TEM images showed presence of nearly spherical particles.

  DOI：

  10.1080/15533174.2010.522674