zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethylphorphyrinate)(1,2-diaminoethane) | 1083099-99-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethylphorphyrinate)(1,2-diaminoethane)
• 英文别名: [Zn(3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin)(monoethyldiamine)]
• CAS: 1083099-99-3
• 化学式: C₃₄H₄₄N₆Zn
• 分子量: 602.154
• InChiKey: NAZUYZVGRIFNKK-FVZPTBRNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙二胺 、 zinc 3,7,13,17-tetramethyl-2,8,12,18-tetraethylporphyrin 以 甲苯 为溶剂， 生成 zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethylphorphyrinate)(1,2-diaminoethane)
  参考文献：
  名称：

  Complexation of zinc octaalkylporphyrin with mono-, di-, and triethylenediamines in toluene

  摘要：

  The complexation of zinc octaalkylporphyrin with mono-, di-, and triethylenediamines in toluene was studied by spectrophotometry using the molar ratio method and by H-1 NMR. The effect of the structure of the two-center organic base on the formation of 1 : 1 or 2 : 1 metal porphyrin-ligand complex was established. The stability constants of the resulting complexes were calculated and the concentration ranges of their existence were determined.

  DOI：

  10.1134/s0036023607080104

文献信息

• The effect of the structure of aliphatic diamines on their interaction with zinc porphyrinates
  作者：G. M. Mamardashvili、O. M. Kulikova、N. Zh. Mamardashvili、O. I. Koifman

  DOI：10.1134/s1070328408060067

  日期：2008.6

  The complex formation of zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethylporphyrinate, 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28-dihydroxycalic-[4]-arene, and 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28-crwon-[6]-calix-[4]-arene with 1,2-diaminoethane, 1,3-diaminopropane, and 1,2-di-(dimethylamino)ethane in toluene was studied by spectrophotometric molar ratio method and H-1 NMR. The effect of the diamine structure on the formation of "internal" and "external" porphyrinate-ligand complexes of the composition 1 :1 and 1 :2 was established. The stability constants of the complexes obtained were calculated and the concentration intervals of their formation were determined.