[(PhCH2)2Sn(3-hydroxy-2-pyridinecarboxylate)2] | 866553-19-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [(PhCH2)2Sn(3-hydroxy-2-pyridinecarboxylate)2]
• 英文别名: [(PhCH2)2Sn(3-OH-2-pic)2]
• CAS: 866553-19-7
• 化学式: C₂₆H₂₂N₂O₆Sn
• 分子量: 577.18
• InChiKey: SLIPNFGZZUDWRY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-羟基-2-吡啶甲酸 、 二氯-二(苯基甲基)锡烷 在 sodium ethoxide 作用下， 以 苯 为溶剂， 以86%的产率得到[(PhCH2)2Sn(3-hydroxy-2-pyridinecarboxylate)2]
  参考文献：
  名称：

  Syntheses and crystal structures of diorganotin (IV) moieties with 3-hydroxy-2-pyridinecarboxylic acid

  摘要：

  A series of new organotin (IV) complexes with 3-hydroxy-2-pyridinecarboxylic acid (3-OH-2-picH) of two types: R2SnCl(3-OH2-pic) (I) (R = Me 1, n-Bu 2, Ph 3, PhCH2 4) and R-2 Sn(3-OH-2-pic)(2) (II) (R = Me 5, n-Bu 6, Ph 7, PhCH2 8) have been synthesized by reactions of diorganotin (IV) dichloride with 3-hydroxy-2-pyridinecarboxylic acid in the presence of sodium ethoxide. All complexes are characterized by elemental analyses, IR spectra and NMR spectra analyses. Among them, complexes 1, 5, 6 and 7 are also characterized by X-ray crystallography diffraction analyses. Complex I is a ID polymeric chain with six-coordinate tin atoms and the packing of complex 1 is stabilized by the C-(HCl)-Cl-... intermolecular weak interactions, thus a 2D network of 1 is formed. Complex 5 is also a ID polymeric chain with seven-coordinate tin atoms. Complex 6 is a zigzag polymeric chain linked by (SnO)-O-... intermolecular weak interactions. Complex 7 is a monomeric complex with distorted octahedral geometry. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.007