toluene-3,4-dithiolatobismuth(III) i-propyldithiocarbonate | 752205-56-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: toluene-3,4-dithiolatobismuth(III) i-propyldithiocarbonate
• CAS: 752205-56-4
• 化学式: C₁₁H₁₃BiOS₄
• 分子量: 498.468
• InChiKey: PBSULWIJQAXJEN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.67
• 重原子数：
  17.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  toluene-3,4-dithiolatobismuth(III) chloride 、 potassium isopropylxanthate 以 二硫化碳 、 丙酮 为溶剂， 以97%的产率得到toluene-3,4-dithiolatobismuth(III) i-propyldithiocarbonate
  参考文献：
  名称：

  Synthesis and Characterization of Some Toluene‐3,4‐dithiolatobismuth(III) Alkyl Dithiocarbonates

  摘要：

  Some mixed toluene-3,4-dithiolatobismuth(III) alkyl dithiocarbonate derivatives of the type SC6II3(CH3)SBiS2COR (where R = Me, Et. n-Pr, i-Pr n-Bu, and i-Bu) have been synthesized by the reaction of the potassium salts of alkyl dithiocarbonates and toluene-3,4-dithiolatobismuth(ill) chloride in equimolar ratio in an anhydrous carbon disulfide/acetone mixture. These newly synthesized derivatives have been characterized by elemental analyses, melting point determinations, as well as IR and NMR spectral studies. On the basis of these studies, tentative structures for these derivatives have been proposed.

  DOI：

  10.1081/sim-120028304