toluene-3,4-dithiolatobismuth(III) chloride | 21846-98-0

• 英文名称: toluene-3,4-dithiolatobismuth(III) chloride
• CAS: 21846-98-0
• 化学式: C₇H₆BiClS₂
• 分子量: 398.69
• InChiKey: OBGCROQFKMPVHQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  toluene-3,4-dithiolatobismuth(III) chloride 、 异丁基黄原酸钾 以 二硫化碳 、 丙酮 为溶剂， 以88%的产率得到toluene-3,4-dithiolatobismuth(III) i-butyldithiocarbonate
  参考文献：
  名称：

  Synthesis and Characterization of Some Toluene‐3,4‐dithiolatobismuth(III) Alkyl Dithiocarbonates

  摘要：

  Some mixed toluene-3,4-dithiolatobismuth(III) alkyl dithiocarbonate derivatives of the type SC6II3(CH3)SBiS2COR (where R = Me, Et. n-Pr, i-Pr n-Bu, and i-Bu) have been synthesized by the reaction of the potassium salts of alkyl dithiocarbonates and toluene-3,4-dithiolatobismuth(ill) chloride in equimolar ratio in an anhydrous carbon disulfide/acetone mixture. These newly synthesized derivatives have been characterized by elemental analyses, melting point determinations, as well as IR and NMR spectral studies. On the basis of these studies, tentative structures for these derivatives have been proposed.

  DOI：

  10.1081/sim-120028304
• 作为产物：
  描述：

  甲苯-3,4-二硫酚 、 氯化铋 以 苯 为溶剂， 生成 toluene-3,4-dithiolatobismuth(III) chloride
  参考文献：
  名称：

  Synthesis and Characterization of Some Toluene‐3,4‐dithiolatobismuth(III) Alkyl Dithiocarbonates

  摘要：

  Some mixed toluene-3,4-dithiolatobismuth(III) alkyl dithiocarbonate derivatives of the type SC6II3(CH3)SBiS2COR (where R = Me, Et. n-Pr, i-Pr n-Bu, and i-Bu) have been synthesized by the reaction of the potassium salts of alkyl dithiocarbonates and toluene-3,4-dithiolatobismuth(ill) chloride in equimolar ratio in an anhydrous carbon disulfide/acetone mixture. These newly synthesized derivatives have been characterized by elemental analyses, melting point determinations, as well as IR and NMR spectral studies. On the basis of these studies, tentative structures for these derivatives have been proposed.

  DOI：

  10.1081/sim-120028304

文献信息

• Toluene-3,4-dithiol (H2tdt) complexes of group 5B halides. Observations of lone-pair stereochemical activity and redox behaviour. Crystal and molecular structures of [AsCl(tdt)] and [PPh4][Sb(tdt)3]
  作者：Jonathan M. Kisenyi、Gerald R. Willey、Michael G. B. Drew、Shem O. Wandiga

  DOI：10.1039/dt9850000069

  日期：——

  remove this proton to give the anion [Sb(tdt)2]– have been unsuccessful. For the [Y][Sb(tdt)3] complexes, obtained following 1:3 addition, all ligand (SH) protons are removed and an X-ray crystal structure determination for Y = PPh4 shows the anion as a slightly distorted octahedron following aerial oxidation SbIII→SbV. Crystals of [AsCl(tdt)](1) are monoclinic, space group P21/c, Z= 4, a= 6.127(5), b=

  甲苯3,4-二硫醇（H 2 tdt）与5B氯化物MCl 3（M = As，Sb或Bi）的反应已在不同化学计量学的条件下进行了研究。[MCl（tdt）]（M = As，Sb或Bi），[Sb（Htdt）（tdt）]，[NEt 3 H] [Bi（tdt）2 ]和[Y] [Sb （tdt）3 ]（Y = NEt 4或PPh 4）已被分离并通过光谱数据（ir和1 H nmr）表征。对于[MCl（tdt）]系列，在1：1加成后获得，配体（SH）质子以HCl的形式除去，并确定了与M III相关的孤电子对具有完全立体化学参与的四面体几何结构，其中M = As由一个X射线晶体结构测定。由1：2加成生成的复合物[Sb（Htdt）（tdt）]和[NEt 3 H] [Bi（tdt）2 ]完全不同，只有后者经历了配体（SH）质子的完全置换。对于[Sb（Htdt）（tdt）]，有很强的证据表明配体（SH）质子之一保持完整，从而产生了基于Sb
• Dialkyldithiocarbamate derivatives of toluene-3,4-dithiolato arsenic(III) and -bismuth(III): synthetic, spectral and single crystal X-ray structural studies
  作者：H.P.S. Chauhan、Kavita Kori、Nagulu Meera Shaik、Sanjay Mathur、Volker Huch

  DOI：10.1016/j.poly.2004.10.007

  日期：2005.1

  We report here on dialkyldithiocarbamates complexes of the type [C6H3(CH3)S2MS2CNR2] (M = As and Bi: R = CH3, C2H5, and CH2-CH2), prepared by the reaction of toluene-3,4-dithiolatoarsenic(III) and -bismuth(III) chlorides [C6H3(CH3)S2MCl] (M = As and Bi) with sodium/ammonium salts of dialkyldithiocarbamates [XS2CNR2] (X = Na and NH4: R = CH3, C2H5 and CH2-CH2). The new derivatives were characterized by melting point, elemental analysis (C, H, N, S and As/Bi) and spectroscopic studies (IR, H-1 and C-13 NMR). Single crystal X-ray diffraction analyses of toluene-3.4-dithiolatoarsenic(III) dimethyldithiocarbamate and toluene-3,4-dithiolatoarsenic(III) pyrrolidine-dithiocarbamate revealed a monodentate chelating mode of the dimethyl as well as the pyrrolidine-dithiocarbamate moieties in these complexes. (C) 2004 Elsevier Ltd. All rights reserved.