1-deuterio-3-(deuteriomethyl)nonane | 122348-19-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-deuterio-3-(deuteriomethyl)nonane
• CAS: 122348-19-0
• 化学式: C₁₀H₂₂
• 分子量: 144.269
• InChiKey: PLZDDPSCZHRBOY-PBNXXWCMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.0
• 重原子数：
  10.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1-乙基-3-(正己基)铝环戊烷 在 重水 作用下， 生成 1-deuterio-3-(deuteriomethyl)nonane
  参考文献：
  名称：

  First preparative synthesis of alumocyclopentanes involving zirconium complexes

  摘要：

  DOI：

  10.1007/bf00953739

文献信息

• Kinetics of Zr-Catalyzed Cycloalumination of Alkenes and Alkynes in the Dzhemilev Reaction
  作者：I. R. Ramazanov、R. N. Kadikova

  DOI：10.1134/s0023158420010085

  日期：2020.1

  AbstractThe kinetics and chemoselectivity of cycloalumination of 1-octene and 4-octyne with Et3Al in the presence of a catalytic amount of Cp2ZrCl2 in hexane at various temperatures and ratios between reactants was studied. It was found that chemoselectivity for the formation of aluminacyclopentanes and aluminacyclopentenes was improved and the reaction time was significantly shortened when the cycloalumination

  摘要研究了在不同温度下，在己烷中催化量的Cp 2 ZrCl 2存在下，Et 3 Al与Et 3 Al环铝烷基化铝的动力学和化学选择性，以及反应物之间的比例。发现在升高的温度（40℃）和不饱和化合物之间的等摩尔比（4-辛烯或1-辛烯）和Et 3 Al。获得了许多烯烃和炔烃（包括功能取代的那些）的反应性的定量特征。
• Cyclomagnesation of Olefins with Ethylmagnesium Bromide in the Presence of Titanium Complexes
  作者：U. M. Dzhemilev、V. A. D’yakonov、L. O. Khafizova、A. G. Ibragimov

  DOI：10.1007/s11178-005-0169-z

  日期：2005.3

  Cyclomagnesation of terminal and cyclic olefins and 1,2-dienes with RMgHlg and R2Mg in the presence of dichloro(dicyclopentadienyl)titanium(IV) gives non-Grignard cyclic and acyclic organomagnesium compounds. The reaction direction depends on the structure of unsaturated initial compound. The most probable reaction mechanism is discussed.

  在二氯（二环戊二烯基）钛（IV）存在下，末端和环状烯烃及 1,2-二烯与 RMgHlg 和 R2Mg 发生环镁反应，生成非格氏环状和非环状有机镁化合物。反应方向取决于不饱和初始化合物的结构。讨论了最可能的反应机理。
• Zirconium-catalyzed reaction of terminal alkenes with triethylindium
  作者：I. R. Ramazanov、L. K. Dil’mukhametova、U. M. Dzhemilev

  DOI：10.1134/s1070428013090017

  日期：2013.9

  Terminal alkenes (undec-1-ene, oct-1-ene, and allylbenzene) reacted with triethylindium in the presence of a catalytic amount of Cp2ZrCl2 in hexane to give mixtures of three organoindium compounds whose hydrolysis in D2O afforded 2-substituted 1,4-dideuterobutane containing minor amounts of 2-substituted 1- and 4-deuterobutanes.

  在催化量的Cp 2 ZrCl 2在己烷中的存在下，末端烯烃（十一碳烯，十一碳烯和烯丙基苯）与三乙基铟反应，得到三种有机铟化合物的混合物，在D 2 O中水解得到2含有少量2-取代的1-和4-氘代丁二酮的1-取代的1，4-二氟代丁烷丁烷。
• A zirconium catalysed synthesis of 1,4-dimagnesium reagents.
  作者：Dorian P. Lewis、Philippe M. Muller、Richard J. Whitby、Raymond V.H. Jones

  DOI：10.1016/s0040-4039(00)93606-2

  日期：1991.11

  The zirconium catalysed addition of diethylmagnesium to a variety of unactivated alkenes affords either the simple carbometallation product, or, 1,4-dimagnesium reagents depending on the conditions and substrate. The products can be successfully functionalised with a variety of electrophiles.

  锆催化将二乙基镁加成到各种未活化的烯烃中，根据条件和底物的不同，可以提供简单的碳金属化产物或1,4-二镁试剂。该产品可以成功地通过各种亲电试剂进行功能化。
• Joint cycloalumination of ethylene and other unsaturated compounds with EtAlCl2 in the presence of Cp2ZrCl2. Synthesis of aluminacarbocycles
  作者：A. G. Ibragimov、L. O. Khafizova、L. I. Khusainova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428010040032

  日期：2010.4

  A procedure has been developed for the selective synthesis of five-membered aluminum-containing heterocycles, 2,3-dialkyl-1-ethylaluminacyclopent-2-enes, 3-alkyl-1-ethylaluminacyclopentanes, 2-alkylidene-1-ethylaluminacyclopentanes, and 3-alkyl-1-ethyl-2-methylidenealuminacyclopentanes, via joint cycloalumination of ethylene and other unsaturated compounds (acetylenes, olefins, and allenes) with EtAlCl2 in the presence of Cp2ZrCl2 as catalyst.