9-(4-bromo-2,5-bis((2-ethylhexyl)oxy)styryl)-8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline | 1160424-48-5

• 分子结构分类: 有机化合物
• 英文名称: 9-(4-bromo-2,5-bis((2-ethylhexyl)oxy)styryl)-8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline
• CAS: 1160424-48-5
• 化学式: C₅₂H₈₆BrNO₄Si
• 分子量: 897.249
• InChiKey: RCOKJAZTHXXZEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.94
• 重原子数：
  59.0
• 可旋转键数：
  25.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  40.16
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  9-(4-bromo-2,5-bis((2-ethylhexyl)oxy)styryl)-8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline 、 N,N-二甲基甲酰胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 3.0h， 以45%的产率得到
  参考文献：
  名称：

  Thermally Stable Nonlinear Optical Polymers Based on Polyimides Substituted with Chromophores Containing Julolidine Moiety

  摘要：

  We designed and synthesized a NLO chromophore adopting the concept of shape modification as well as possessing high thermal stability. The chromophore was featured by a phenylene ring as a conjugation bridge, a bulky alkyl chain attached on the side of the conjugation bridge, and julolidine moiety as an electron donor. The NLO chromophore was attached to the polyimide as a side chain, resulting in thermally durable NLO polymers. On set decomposition temperature of the NLO chromophore was measured 330 degrees C in TGA analysis. The NLO polymer exhibited high glass transition temperature of 150 degrees C and was thermally stable up to 250 degrees C. The polymer was quite soluble in common solvents and produced an optical quality film by spin-coating. The electro-optic coefficient of the film was measured using 1.55 mu m laser source, giving as high as 30 pm/V at the poling condition of 150 degrees C and 1 MV/cm.

  DOI：

  10.1080/15421400802329590
• 作为产物：
  描述：

  diethyl [[2,5-bis(2-ethylhexyloxy)-4-bromophenyl]methyl]phosphonate 、 8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline-9-carbaldehyde 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以86%的产率得到9-(4-bromo-2,5-bis((2-ethylhexyl)oxy)styryl)-8-((6-((tert-butyldimethylsilyl)oxy)hexyl)oxy)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline
  参考文献：
  名称：

  Thermally Stable Nonlinear Optical Polymers Based on Polyimides Substituted with Chromophores Containing Julolidine Moiety

  摘要：

  We designed and synthesized a NLO chromophore adopting the concept of shape modification as well as possessing high thermal stability. The chromophore was featured by a phenylene ring as a conjugation bridge, a bulky alkyl chain attached on the side of the conjugation bridge, and julolidine moiety as an electron donor. The NLO chromophore was attached to the polyimide as a side chain, resulting in thermally durable NLO polymers. On set decomposition temperature of the NLO chromophore was measured 330 degrees C in TGA analysis. The NLO polymer exhibited high glass transition temperature of 150 degrees C and was thermally stable up to 250 degrees C. The polymer was quite soluble in common solvents and produced an optical quality film by spin-coating. The electro-optic coefficient of the film was measured using 1.55 mu m laser source, giving as high as 30 pm/V at the poling condition of 150 degrees C and 1 MV/cm.

  DOI：

  10.1080/15421400802329590