[Cu(II)(S-methyl-3-(4-methoxybenzylidine)dithiocarbazate)2] | 76067-33-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Cu(II)(S-methyl-3-(4-methoxybenzylidine)dithiocarbazate)2]
• 英文别名: [Cu(II)(S-methyl-3-(4-methoxybenzylidine)dithiocarbazate)₂]；[Cu(II)(NS)₂]
• CAS: 76067-33-9
• 化学式: C₂₀H₂₂CuN₄O₂S₄
• 分子量: 542.23
• InChiKey: LUZXASRRSKQGPT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-甲氧基苯甲醛 以 乙醇 为溶剂， 反应 0.83h， 生成 [Cu(II)(S-methyl-3-(4-methoxybenzylidine)dithiocarbazate)2]
  参考文献：
  名称：

  Synthesis, characterization, and antimicrobial activity of complexes of Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II), and U(VI) containing bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine)dithiocarbazate]

  摘要：

  A novel bidentate Schiff base containing NS donor sequences was synthesized by condensing S-methyldithiocarbazate (SMDTC) with p-anisaldehyde. A series of complexes of the ligand with Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II) and U(VI) were studied and characterized by various physico-chemical methods. Cu(II), Ni(II) and Zn(II), Pb(II) complexes were four-coordinate with square plannar and tetrahedral geometry respectively. Co(II), Mn(II), and U(VI) complexes were six-coordinate with octahedral geometry. Antimicrobial activity of the prepared complexes was tested as resistance to antimicrobial agents in a wide variety of nosocomial and community-acquired pathogens. The highest antimicrobial activity was detected for the complex Co(II) against candida species.

  DOI：

  10.1134/s1070363215040350

文献信息

• Coordination compounds of hydrazine derivatices with transition metals—XIX
  作者：M.F. Iskander、L. El-Sayed、A. El-Toukhy

  DOI：10.1016/0022-1902(80)80426-x

  日期：1980.1