(1R,2R)-1-((3aS,6S,7S,7aS)-7-acetoxy-5-acetyl-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-yl)propane-1,2,3-triyl triacetate | 1236041-37-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (1R,2R)-1-((3aS,6S,7S,7aS)-7-acetoxy-5-acetyl-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-yl)propane-1,2,3-triyl triacetate
• CAS: 1236041-37-4
• 化学式: C₂₁H₃₁NO₁₁
• 分子量: 473.477
• InChiKey: UOAZCBSJTUENTC-XSEPRYCASA-N

反应信息

• 作为反应物：
  描述：

  (1R,2R)-1-((3aS,6S,7S,7aS)-7-acetoxy-5-acetyl-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-yl)propane-1,2,3-triyl triacetate 在 盐酸 作用下， 以 水 为溶剂， 反应 7.0h， 以70%的产率得到(2S,3S,4S,5S)-2-((1R,2R)-1,2,3-trihydroxypropyl)pyperidine-3,4,5-triol
  参考文献：
  名称：

  Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from d-xylose

  摘要：

  The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2010.04.016
• 作为产物：
  描述：

  、 乙酸酐 在 吡啶 作用下， 以 乙醇 为溶剂， 反应 20.0h， 生成 (1R,2R)-1-((3aS,6S,7S,7aS)-7-acetoxy-5-acetyl-2,2-dimethyl-hexahydro-[1,3]dioxolo[4,5-c]pyridin-6-yl)propane-1,2,3-triyl triacetate
  参考文献：
  名称：

  Synthesis of 1,4-dideoxy-1,4-iminoheptitol and 1,5-dideoxy-1,5-iminooctitols from d-xylose

  摘要：

  The synthesis of iminosugars from inexpensive D-xylose in high yields has been developed. The key step in this synthesis involves Wittig olefination or chelation-controlled attack of Grignard reagents on lactol and ring-closing metathesis using first or second generation Grubbs' catalysts. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2010.04.016