[Ag(3-bromoquinoline)2(nitrato)] | 1378262-68-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Ag(3-bromoquinoline)2(nitrato)]
• CAS: 1378262-68-0
• 化学式: C₁₈H₁₂AgBr₂N₃O₃
• 分子量: 585.988
• InChiKey: OGHYZZBEQBYVFL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  3-溴喹啉 、 silver nitrate 以 乙醇 、 水 为溶剂， 以71%的产率得到[Ag(3-bromoquinoline)2(nitrato)]
  参考文献：
  名称：

  Molecular structure and vibrational spectra of free and coordinated 3-bromoquinoline: Unexpected intramolecular CH⋯O interactions

  摘要：

  Combined experimental and theoretical vibrational spectra of 3-bromoquinoline (3BrQ) and its silver(I) nitrato complex [Ag(3BrQ)(2)NO3] have been reported. The geometry of the free and Coordinated 3BrQ molecules; [Ag(3BrQ)(2)NO3] were optimized using HF and DFT/B3LYP methods using 6-31G(d,p) basis set for all atoms except for silver atom where the LANL08 basis set is used. The calculated molecular geometry of the Silver(I) complex predicted a distorted tetrahedral arrangement around the silver atom where the Ag(I) is coordinated to two 3BrQ ligands and one bidentate nitrate through two oxygen atoms. Also the calculations predicted the presence of intramolecular C-H center dot center dot center dot O interactions between the oxygen of the nitrate and the neighboring hydrogen atoms of the coordinated 3BrQ which is confirmed by the analysis of the C-H stretching vibrations using total energy distribution (TED%). (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.03.016