tris(3-isopropylphenyl)phosphine | 208183-71-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(3-isopropylphenyl)phosphine
• 英文别名: Tris(3-propan-2-ylphenyl)phosphane
• CAS: 208183-71-5
• 化学式: C₂₇H₃₃P
• 分子量: 388.533
• InChiKey: JZRYKSJKPZLMSW-UHFFFAOYSA-N

物化性质

• 沸点：
  468.1±44.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-溴-3-异丙基苯 在 magnesium 、 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以60%的产率得到tris(3-isopropylphenyl)phosphine
  参考文献：
  名称：

  铜催化芳基和杂芳基酮的不对称加氢

  摘要：

  高通量筛选使得能够开发用于在低至5 bar的H 2压力下进行的前手性芳基和杂芳基酮的不对称氢化的Cu基催化剂体系。（R，S）-N -Me-3，5-二甲苯基-BoPhoz和三（3，5-二甲苯基）膦的配体组合以良好的收率和对映选择性提供了苄醇。辅助三芳基膦的电子和空间特性对于确定反应性和选择性均很重要。

  DOI：

  10.1021/ol4021223

文献信息

• Dissymmetrically Substituted Diphosphines with Two Atropisomeric Axes and Their Application in Asymmetric Hydrogenation of Imines
  作者：Gaspard Hedouin、Racha Abed Ali Abdine、Quentin Dherbassy、Christophe Michon、Ignacio Funes‐Ardoiz、Françoise Colobert、Joanna Wencel‐Delord

  DOI：10.1002/adsc.202300527

  日期：2023.6.20

  diphosphine ligands used in asymmetric catalysis are C2-symmetric and their structural modifications are often limited. Herein, we reported the design of original enantiopure dissymmetrical diphosphines, BiaxPhos, bearing two atropisomeric axes. Their original chiral architecture combined with important modularity, renders BiaxPhos ligands appealing candidates for asymmetric catalysis, as illustrated

  尽管具有巨大的潜力和广泛的应用，但用于不对称催化的大多数二膦配体是C 2-对称且它们的结构修饰通常是有限的。在此，我们报道了带有两个阻转异构轴的原始对映纯不对称二膦 BiaxPhos 的设计。其原始的手性结构与重要的模块化相结合，使 BiaxPhos 配体成为不对称催化的有吸引力的候选者，如 Ir-BiaxPhos 催化的不对称亚胺氢化所示，在温和条件下为手性胺提供了优异的对映选择性。值得注意的是，结合实验机理研究和 DFT 计算描绘了尚未探索的机理场景，这意味着烯胺互变异构形式的氢化而不是亚胺的经典还原。
• Process for producing polybutadiene
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0511015A1

  公开（公告）日：1992-10-28

  A process for producing a polybutadiene, which comprises polymerizing 1,3-butadiene in an inert organic solvent with a catalyst comprising (A) a cobalt compound, (B) an organoaluminum compound consisting essentially of an aluminoxane and, if necessary, (C) a tertiary phosphine compound, (D) at least one compound selected from the group consisting of an ester compound, an alcohol compound, a phenolic compound, a sulfoxide compound, a nitrogen-containing heterocyclic compound, water and a tertiary amine compound and (E) at least one compound selected from the group consisting of carbon disulfide, a xanthogen compound and a thioisocyanide. By this process, there can be produced, as desired, a cis-1,4-polybutadiene, a 1,2-polybutadiene having a desired vinyl content, a crystalline 1,2-polybutadiene or a polybutadiene containing crystalline 1,2-polybutadiene segments.

  一种生产聚丁二烯的工艺，它包括在惰性有机溶剂中用催化剂聚合 1，3-丁二烯，催化剂包括(A)钴化合物，(B)主要由铝氧烷组成的有机铝化合物，必要时，(C)叔膦化合物、(D) 至少一种从酯类化合物、醇类化合物、酚类化合物、亚砜类化合物、含氮杂环类化合物、水和叔胺类化合物中选出的化合物，以及 (E) 至少一种从二硫化碳、黄原化合物和硫代异氰化物中选出的化合物。通过这种工艺，可以生产出所需的顺式-1,4-聚丁二烯、具有所需乙烯基含量的 1,2-聚丁二烯、结晶 1,2-聚丁二烯或含有结晶 1,2-聚丁二烯段的聚丁二烯。
• 1,2-POLYBUTADIENE, THERMOPLASTIC ELASTOMER COMPOSITION AND POLYMER COMPOSITION
  申请人：JSR Corporation

  公开号：EP1306396A1

  公开（公告）日：2003-05-02

  The 1,2-polybutadiene of the present invention, the 1,2- bond content in butadiene unit is 70% by weight or more, a melting point is in a range of 50-140°C, the viscosity η measured with a slit die rheometer at a shear rate of 5113sec-1 is in a range of 400-1200 poises at 120°C in a range of 300-1000 poises at 150°C, and in a range of 200-800 poises at 180°C, and a total halogen content is 30ppm and less. When this is molded at a high temperature, a problem of the mold contamination, the thermal deterioration and change in the physical properties with time is improved, the molded article has the excellent properties such as the moldability, the transparency, the mechanical strength property, the wet skid resistance and the like, and is suitably used as a thermoplastic elastomer such as industrial parts and various molded articles such as footwears, various sheets, films and the like. In addition, 1,2-polybutadiene of the present invention has a molding temperature of about 15°C, being low among thermoplastic elastomers, and is also advantageous in respect of the energy. In addition, since 1,2-polybutadiene of the present invention can be vulcanized, and is excellent in a degree of the peroxide cross-linking activity and the filling property for a filler and a drug, it can be utilized as a vulcanizing rubber, or as a reaction aid for other vulcanizing rubbers. In addition, the thermoplastic elastomer composition of the present invention contains other thermoplastic elastomer and the aforementioned 1,2-polybutadiene and, when this is molded, the excellent nature such as moldability, the molded article appearance and the scratch resistance is exhibited.

  本发明的 1,2-聚丁二烯，丁二烯单元中的 1,2 键含量为 70%（重量比）或更高，熔点在 50-140°C 范围内，在剪切速率为 5113sec-1 时用缝模流变仪测量的粘度 η 在 120°C 时在 400-1200 poises 范围内，在 150°C 时在 300-1000 poises 范围内，在 180°C 时在 200-800 poises 范围内，总卤素含量在 30ppm 及以下。在高温下成型时，模具污染、热变质和物性随时间变化的问题得到改善，成型品具有良好的成型性、透明性、机械强度特性、防滑性等特性，适合用作热塑性弹性体，如工业部件和各种成型品，如鞋类、各种片材、薄膜等。此外，本发明的 1,2-聚丁二烯的成型温度约为 15°C，在热塑性弹性体中较低，在能量方面也具有优势。此外，由于本发明的 1,2-聚丁二烯可以硫化，并且在一定程度上具有优异的过氧化物交联活性以及填充剂和药物的填充性能，因此可以用作硫化橡胶或其他硫化橡胶的反应助剂。此外，本发明的热塑性弹性体组合物含有其他热塑性弹性体和上述 1,2-聚丁二烯，在模塑时，可表现出良好的可模塑性、模塑品外观和抗划伤性。
• OIL EXTENDED 1, 2-POLYBUTADIENE AND METHOD OF MANUFACTURING THE POLYBUTADIENE, AND COMPOSITION AND FORMED PRODUCT THEREOF
  申请人：JSR Corporation

  公开号：EP1369454A1

  公开（公告）日：2003-12-10

  Disclosed are oil-extended 1,2-polybutadiene containing an extender oil in a specific amount based on 1, 2-polybutadiene and a production method thereof, and a composition further containing another (co)polymer, a foaming agent, a crosslinking agent, a softening agent and other additives. The resulting oil-extended 1,2-polybutadiene and the composition thereof has excellent functions characterizing conventional 1,2-polybutadiene and is further excellent in wear resistance, fluidity (processability), coloring properties (high distinctness of images), flexibility, attachability and the like, so that they can be applied to various formed articles, shoe sole materials and laminate having high performances.

  本发明公开了以 1,2-聚丁二烯为基础、含有一定量扩展油的油扩展 1,2-聚丁二烯及其生产方法，以及进一步含有另一种（共）聚合物、发泡剂、交联剂、软化剂和其他添加剂的组合物。由此得到的油浸 1，2-聚丁二烯及其组合物具有传统 1，2-聚丁二烯所具有的优异功能，并在耐磨性、流动性（加工性）、着色性能（图像清晰度高）、柔韧性、附着性等方面更加优异，因此可用于各种成型制品、鞋底材料和具有高性能的层压板。
• RESIN MOLDING AND WORKED ITEM THEREFROM
  申请人：JSR Corporation

  公开号：EP1607434A1

  公开（公告）日：2005-12-21

  A resin molded article which is a molded article obtained by irradiating a resin molded article containing 100 to 60 parts by weight of (A) syndiotactic 1,2-polybutadiene having a crystallinity of 5% or more and 0 to 40 parts by weight of (B) another thermoplastic polymer with an electron beam, in which the 50% stress of the molded article after the electron beam irradiation (50% M: M2) is from 1.01 to 2.5 times the 50% stress before the electron beam irradiation (50% M: M1), and the molded article has steam sterilization resistance. The molded article is excellent in flexibility and hardness, excellent in steam sterilization resistance, and useful for medical applications such as an infusion tube, an infusion solution container, a catheter and the like.

  一种树脂模塑制品，它是用电子束辐照含有 100 至 60 份（重量百分比）结晶度为 5%或以上的(A)辛二共聚聚丁二烯和 0 至 40 份（重量百分比）另一种热塑性聚合物的树脂模塑制品而得到的模塑制品，其中电子束辐照后模塑制品的 50%应力（50% M：M2）是电子束辐照前 50%应力（50% M：M1）的 1.电子束辐照后模塑品的 50% 应力（50% M：M2）是电子束辐照前 50% 应力（50% M：M1）的 1.01 至 2.5 倍，且模塑品具有耐蒸汽灭菌性。该模塑品具有出色的柔韧性和硬度，耐蒸汽灭菌性出色，可用于输液管、输液容器、导管等医疗应用。