| 733741-66-7

• CAS: 733741-66-7
• 化学式: C₂₁H₂₈FeN₂O₂
• 分子量: 396.313
• InChiKey: YLITXSSRKCPZDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  哌啶 、 1'-iodo-N,N-diethyl ferrocenecarboxamide 、 一氧化碳 在 palladium diacetate 三乙胺 、 三苯基膦 作用下， 以 甲苯 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Aminocarbonylation of 1,1′-diiodoferrocene, two-step synthesis of heterodisubstituted ferrocene derivatives via homogeneous catalytic carbonylation/coupling reactions

  摘要：

  Detailed investigation of the catalytic carbonylation of 1, 1'-diiodoferrocene has been carried out. The importance of the 1'-iodoferrocenecarboxamide- or 1'-iodo-ferroceneglyoxylic amide-type products as starting materials for the synthesis of various heterodisubstituted ferrocenes, that can serve as starting materials for ferrocene-based biosensors, was also proved. The potential of this reaction sequence was shown by the high-yielding synthesis of 1'-vinyl ferrocenecarboxamide/glyoxylic amide and 1'-acyl ferrocencarboxamide derivatives. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.046