(2R,3R)-4-oxo-2,3-bis(tetradecanoyloxy)-4-(((2R,3S,4S,5R,6R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)methoxy)butanoic acid | 1390665-44-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (2R,3R)-4-oxo-2,3-bis(tetradecanoyloxy)-4-(((2R,3S,4S,5R,6R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)methoxy)butanoic acid
• CAS: 1390665-44-7
• 化学式: C₃₈H₆₈O₁₃
• 分子量: 732.95
• InChiKey: BDOIVAPEZUWPIC-MTUXOXGOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.64
• 重原子数：
  51.0
• 可旋转键数：
  31.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  206.35
• 氢给体数：
  5.0
• 氢受体数：
  12.0

反应信息

• 作为产物：
  描述：

  肉豆蔻酰氯 在 吡啶 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 96.0h， 生成 (2R,3R)-4-oxo-2,3-bis(tetradecanoyloxy)-4-(((2R,3S,4S,5R,6S)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)methoxy)butanoic acid 、 (2R,3R)-4-oxo-2,3-bis(tetradecanoyloxy)-4-(((2R,3S,4S,5R,6R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)methoxy)butanoic acid
  参考文献：
  名称：

  Amphiphiles Based on d-Glucose: Efficient Low Molecular Weight Gelators

  摘要：

  A series of novel amphiphiles were synthesized based entirely on renewable resources. Besides their efficacy as supramolecular gelators in a wide variety of organic solvents and also water, their surface properties as surfactants and emulsifiers have been determined. A methodical study revealed that the length of the hydrocarbon chains has a dramatic and decisive influence on the thermal stabilities of the obtained hydrogels.

  DOI：

  10.1021/ol300555a