bis(1,3-bis(2-tert-butyltetrazol-5-yl)triazenide)cobalt(II) | 1253041-86-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: bis(1,3-bis(2-tert-butyltetrazol-5-yl)triazenide)cobalt(II)
• CAS: 1253041-86-9
• 化学式: C₂₀H₃₆CoN₂₂
• 分子量: 643.646
• InChiKey: GVGNXEYGOQFBRT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1,3-bis(2-tert-butyltetrazol-5-yl)triazene 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以74%的产率得到bis(1,3-bis(2-tert-butyltetrazol-5-yl)triazenide)cobalt(II)
  参考文献：
  名称：

  1,3-Bis(2-alkyltetrazol-5-yl)triazenes and their Fe(II), Co(II) and Ni(II) complexes: Synthesis, spectroscopy, and thermal properties. Crystal structure of Fe(II) and Co(II) 1,3-bis(2-methyltetrazol-5-yl)triazenide complexes

  摘要：

  Complexes ML21 and ML22, with M = Fe-II, Co-II, Ni-II, and 1,3-bis(2-R-tetrazol-5-yl)triazenide ligands L-1 (R = Me) and L-2 (R = Bu-1), have been synthesized by the reaction of corresponding 1,3-bis(2-R-tetrazol-5-yl)triazenes with metal(II) salts in basic media and characterized by IR, UV-Vis spectroscopy, thermal and X-ray diffraction analyses. Both 1,3-bis(2-R-tetrazol-5-yl)triazenes were found to deprotonate on coordination and act as tridentate chelating ligands forming distorted MN6 octahedra around metal(II) cations. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.07.008