(3-phenylundecamethylcyclohexasilanyl)trifluoromethanesulfonate | 173467-57-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: (3-phenylundecamethylcyclohexasilanyl)trifluoromethanesulfonate
• CAS: 173467-57-7
• 化学式: C₁₇H₃₅F₃O₃SSi₆
• 分子量: 545.037
• InChiKey: VXRAOOBTBFRVLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.73
• 重原子数：
  30.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  (3-phenylundecamethylcyclohexasilanyl)trifluoromethanesulfonate 在 lithium aluminium tetrahydride 、 氯仿 作用下， 以 乙二醇二甲醚 、 乙醚 、 二乙二醇二甲醚 、 甲苯 为溶剂， 反应 19.0h， 生成 1,2,2,3,3,4,5,5,6,6,1',2',2',3',3',4',4',5',5',6',6'-Henicosamethyl-4-phenyl-[1,1']bihexasilinanyl
  参考文献：
  名称：

  Synthesis of bi(cyclohexasilanyl) derivatives

  摘要：

  Starting from 1,3- or 1,4-diphenyldecamethylcyclohexasilane, one phenyl group can be split off selectively by action of trifluoromethanesulfonic acid. The syntheses of some new mixed substituted cyclohexasilanes 1,3- and 1,4-Ph-Si(6)Me(10)-X (X = CF3SO3, H, Cl or Br) are reported. By reaction of 1,3- and 1,4-Ph-Si(6)Me(10)-Cl with undecamethylcyclohexasilanyl potassium, novel monophenylated bi(cyclohexasilanyl) derivatives are obtained. The preparation of the corresponding monochlorinated derivatives is also reported.

  DOI：

  10.1016/0022-328x(95)05506-k
• 作为产物：
  描述：

  1,4-dichlorodecamethylcyclohexasilane 以 乙醚 、 甲苯 为溶剂， 生成 (3-phenylundecamethylcyclohexasilanyl)trifluoromethanesulfonate
  参考文献：
  名称：

  Synthesis of bi(cyclohexasilanyl) derivatives

  摘要：

  Starting from 1,3- or 1,4-diphenyldecamethylcyclohexasilane, one phenyl group can be split off selectively by action of trifluoromethanesulfonic acid. The syntheses of some new mixed substituted cyclohexasilanes 1,3- and 1,4-Ph-Si(6)Me(10)-X (X = CF3SO3, H, Cl or Br) are reported. By reaction of 1,3- and 1,4-Ph-Si(6)Me(10)-Cl with undecamethylcyclohexasilanyl potassium, novel monophenylated bi(cyclohexasilanyl) derivatives are obtained. The preparation of the corresponding monochlorinated derivatives is also reported.

  DOI：

  10.1016/0022-328x(95)05506-k