hexanedioic acid monopent-3-yl ester | 855605-57-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexanedioic acid monopent-3-yl ester
• 英文别名: 6-Oxo-6-pentan-3-yloxyhexanoic acid
• CAS: 855605-57-1
• 化学式: C₁₁H₂₀O₄
• 分子量: 216.277
• InChiKey: RWCKPBWFHKFIDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-戊醇 、 反式,反式-1,3-丁二烯-1,4-二羧酸 在 platinum on carbon 、 氢气 作用下， 反应 12.0h， 生成 己二酸 、 hexanedioic acid monopent-3-yl ester
  参考文献：
  名称：

  高效将蔗糖酸转化为己二酸的化学过程和DFT研究hen催化脱氧机理

  摘要：

  用可再生的生物基原料生产散装化学品和燃料对于人类社会的可持续发展具有重要意义。己二酸是生物资源中需求最旺盛的直接化学药品之一，主要用于尼龙6,6聚酰胺的大批量生产。迫切需要开发可持续和环境友好的方法，以从可再生原料生产己二酸。但是，目前没有合适的生物己二酸合成工艺。本文展示了一种高效的合成方案，可通过氧化or络合物催化的脱氧脱水（DODH）反应以及随后的Pt / C催化的转移氢化将黏性酸转化为己二酸。

  DOI：

  10.1002/anie.201310991

文献信息

• [EN] CHEMICAL PROCESS TO CONVERT MUCIC ACID TO ADIPIC ACID<br/>[FR] PROCÉDÉ CHIMIQUE POUR CONVERTIR L'ACIDE MUCIQUE EN ACIDE ADIPIQUE
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2015084265A1

  公开（公告）日：2015-06-11

  The present invention provides a method of synthesizing an ester of a saturated carboxylic acid from a saturated polyhydroxycarboxylic acid by performing a deoxydehydration reaction and a hydrogen transfer reaction.

  本发明提供了一种从饱和多羟基羧酸通过进行脱氧脱水反应和氢转移反应合成饱和羧酸酯的方法。
• [EN] SYNTHESIS OF ALIPHATIC POLYCARBOXYLIC ACID<br/>[FR] SYNTHÈSE D'ACIDE POLYCARBOXYLIQUE ALIPHATIQUE
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2016032403A1

  公开（公告）日：2016-03-03

  The present invention provides a method for synthesizing an aliphatic polycarboxylic acid, the method comprising the steps of: (a) dehydrating a polyhydroxycarboxlic acid using a rhenium-based catalyst to produce an unsaturated polycarboxylic acid precursor; and (b) performing a hydrogenation reaction on the unsaturated polycarboxylic acid precursor to produce the aliphatic polycarboxylic acid.

  本发明提供了一种合成脂肪族多羧酸的方法，该方法包括以下步骤：(a)使用基于铼的催化剂脱水多羟基羧酸，以产生不饱和多羧酸前体；以及(b)对不饱和多羧酸前体进行氢化反应，以产生脂肪族多羧酸。
• NON-AQUEOUS ELECTROLYTE SOLUTION, AND NON-AQUEOUS-ELECTROLYTE SECONDARY CELL USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3252861A1

  公开（公告）日：2017-12-06

  There is provided a non-aqueous electrolyte solution enabling fabrication of a non-aqueous electrolyte solution secondary battery which achieves suppressed gas generation when used under high temperature environment and the improved residual capacity of the battery, and the improved cycle characteristic thereof, and further, is excellent in discharge load characteristic (dischargeable at high rate), and a non-aqueous electrolyte solution secondary battery using the non-aqueous electrolyte solution. There is provided a non-aqueous electrolyte solution for use in a non-aqueous electrolyte solution secondary battery including a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, which solution contains a bismaleimide compound having a specific structure, and a non-aqueous electrolyte solution secondary battery using the solution.

  本发明提供了一种非水电解质溶液，该溶液可用于制造非水电解质溶液二次电池，在高温环境下使用时可抑制气体生成，提高电池的剩余容量，改善循环特性，而且放电负载特性优异（可高速放电），还提供了一种使用该非水电解质溶液的非水电解质溶液二次电池。提供了一种用于非水电解质溶液二次电池的非水电解质溶液，该二次电池包括正极和负极，正极具有能够吸收和释放金属离子的正极活性材料，负极具有能够吸收和释放金属离子的负极活性材料，该溶液含有具有特定结构的双马来酰亚胺化合物，还提供了一种使用该溶液的非水电解质溶液二次电池。
• CHEMICAL PROCESS TO CONVERT MUCIC ACID TO ADIPIC ACID
  申请人：AGENCY FOR SCIENCE TECHNOLOGY AND RESEARCH

  公开号：US20170001944A1

  公开（公告）日：2017-01-05

  The present invention provides a method of synthesizing an ester of a saturated carboxylic acid from a saturated polyhydroxycarboxylic acid by performing a deoxydehydration reaction and a hydrogen transfer reaction.
• NON-AQUEOUS ELECTROLYTE SOLUTION AND NON-AQUEOUS ELECTROLYTE SOLUTION SECONDARY BATTERY USING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20170324116A1

  公开（公告）日：2017-11-09

  There is provided a non-aqueous electrolyte solution enabling fabrication of a non-aqueous electrolyte solution secondary battery which achieves suppressed gas generation when used under high temperature environment and the improved residual capacity of the battery, and the improved cycle characteristic thereof, and further, is excellent in discharge load characteristic (dischargeable at high rate), and a non-aqueous electrolyte solution secondary battery using the non-aqueous electrolyte solution. There is provided a non-aqueous electrolyte solution used in a non-aqueous electrolyte solution secondary battery including a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, which solution contains a bismaleimide compound having a specific structure, and a non-aqueous electrolyte solution secondary battery using the solution.