ethyl 2-(4-pentenyl)-2-vinyl-6-heptenoate | 1447273-90-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: ethyl 2-(4-pentenyl)-2-vinyl-6-heptenoate
• CAS: 1447273-90-6
• 化学式: C₁₆H₂₆O₂
• 分子量: 250.381
• InChiKey: ZGDLUKFPLWZEGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.43
• 重原子数：
  18.0
• 可旋转键数：
  11.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  ethyl 2-(4-pentenyl)-2-vinyl-6-heptenoate 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 1.5h， 以95%的产率得到2-(4-pentenyl)-2-vinyl-6-heptenol
  参考文献：
  名称：

  Preparation of acid-resistant heavy fluorous tags for recycling in synthetic systems

  摘要：

  Acid-resistant heavy fluorous tags, in which all three fluorous chains are tethered in a symmetric manner by carbon-carbon linkage, were designed and synthesized from ethyl crotonate. They were designed also to possess a reactive OH group at a central position, not only for conjugation with a target molecule but also for tag recycling. The tag with an alkyl spacer equipped the primary OH group had the greatest reactivity in conjugation reactions with target molecules and could be recovered in the highest yields, implying its potential for use in recycling applications. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2014.07.014
• 作为产物：
  描述：

  2-丁烯酸乙酯 、 5-溴-1-戊烯 在 六甲基磷酰三胺 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 反应 23.0h， 以76%的产率得到ethyl 2-(4-pentenyl)-2-vinyl-6-heptenoate
  参考文献：
  名称：

  Preparation of acid-resistant heavy fluorous tags for recycling in synthetic systems

  摘要：

  Acid-resistant heavy fluorous tags, in which all three fluorous chains are tethered in a symmetric manner by carbon-carbon linkage, were designed and synthesized from ethyl crotonate. They were designed also to possess a reactive OH group at a central position, not only for conjugation with a target molecule but also for tag recycling. The tag with an alkyl spacer equipped the primary OH group had the greatest reactivity in conjugation reactions with target molecules and could be recovered in the highest yields, implying its potential for use in recycling applications. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2014.07.014

文献信息

• JP6001267
  申请人：——

  公开号：——

  公开（公告）日：——