[Zn(azobenzen-4,4'-dicarboxylic acid(-2H))(H2O)](n) | 1246383-74-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: [Zn(azobenzen-4,4'-dicarboxylic acid(-2H))(H2O)](n)
• 英文别名: [Zn(ADB)(H2O)](n)
• CAS: 1246383-74-3
• 化学式: C₁₄H₈N₂O₄*H₂O*Zn
• 分子量: 351.634
• InChiKey: CZLTUYDTOQCGPI-VRZXRVJBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.0
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  136.48
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [Zn(azobenzen-4,4'-dicarboxylic acid(-2H))(H2O)](n) 以 neat (no solvent, solid phase) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  An unusual 2-fold interpenetrated 3D PtS framework containing circular and rhombic tubular building blocks and hydrogen-bonded –O–metal–O–chain

  摘要：

  Circular and rhombic tubular building blocks interweave mutually into a novel 2-fold interpenetrated 3D PtS framework [Zn(ADB)(H2O)](n) (1) (H(2)ADB = azobenzen-4,4'-dicarboxylic acid), with hydrogen-bonded-O-metal-O-chain. In additional, solid-state properties such as photoluminescence and thermal stability of the complex I have also been studied. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.05.015
• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 水 、 偶氮苯-4,4-二羧酸 在 triethylamine 作用下， 以 水 为溶剂， 以66%的产率得到[Zn(azobenzen-4,4'-dicarboxylic acid(-2H))(H2O)](n)
  参考文献：
  名称：

  An unusual 2-fold interpenetrated 3D PtS framework containing circular and rhombic tubular building blocks and hydrogen-bonded –O–metal–O–chain

  摘要：

  Circular and rhombic tubular building blocks interweave mutually into a novel 2-fold interpenetrated 3D PtS framework [Zn(ADB)(H2O)](n) (1) (H(2)ADB = azobenzen-4,4'-dicarboxylic acid), with hydrogen-bonded-O-metal-O-chain. In additional, solid-state properties such as photoluminescence and thermal stability of the complex I have also been studied. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.05.015