[Pd(II)(μ-acetate)4Co(II)]2(μ-acetate)2Pd(II)(pyridine)2 | 1044509-88-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Pd(II)(μ-acetate)4Co(II)]2(μ-acetate)2Pd(II)(pyridine)2
• CAS: 1044509-88-7
• 化学式: C₃₀H₄₀Co₂N₂O₂₀Pd₃
• 分子量: 1185.9
• InChiKey: JUGNOLQLIOMFEH-UHFFFAOYSA-D

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(II)(μ-acetate)4Co(II)]2(μ-acetate)2Pd(II)(pyridine)2 以 neat (no solvent) 为溶剂， 生成 cobalt(II) oxide 、 钯
  参考文献：
  名称：

  Two-way synthesis of a double-lantern heterobimetallic complex [Pd(μ-OOCMe)4Co]2(μ-OOCMe)2Pd(py)2

  摘要：

  The lantern complex Pd-11(mu-OOCMe)(4)CO11(NCMe) (1) was transformed into the pentanuclear double-lantern acetate-bridged heterobimetallic complex [Pd(mu-OOCMe)(4)Co](2)( mu-OOCMe)(2)Pd(py)(2) (py is pyridine) (2) by two routes: (i) reaction of I with pyridine and (ii) reaction of 1 with trans-Pd(py)(2)(OOCMe)(2)-Complex 2 x 3C(6)H(6) was characterised by single-crystal X-ray diffraction, DTA-TG and magnetic susceptibility data. (c) 2007 Elsevier 13N. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.05.004
• 作为产物：
  描述：

  [Pd(II)(μ-acetate)4Co(II)]2(μ-acetate)2Pd(II)(pyridine)2*3(benzene) 以 neat (no solvent, solid phase) 为溶剂， 生成 [Pd(II)(μ-acetate)4Co(II)]2(μ-acetate)2Pd(II)(pyridine)2
  参考文献：
  名称：

  Two-way synthesis of a double-lantern heterobimetallic complex [Pd(μ-OOCMe)4Co]2(μ-OOCMe)2Pd(py)2

  摘要：

  The lantern complex Pd-11(mu-OOCMe)(4)CO11(NCMe) (1) was transformed into the pentanuclear double-lantern acetate-bridged heterobimetallic complex [Pd(mu-OOCMe)(4)Co](2)( mu-OOCMe)(2)Pd(py)(2) (py is pyridine) (2) by two routes: (i) reaction of I with pyridine and (ii) reaction of 1 with trans-Pd(py)(2)(OOCMe)(2)-Complex 2 x 3C(6)H(6) was characterised by single-crystal X-ray diffraction, DTA-TG and magnetic susceptibility data. (c) 2007 Elsevier 13N. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.05.004