[ClRh(III)(phthalocyaninate(2-))] | 14285-57-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [ClRh(III)(phthalocyaninate(2-))]
• 英文别名: chloro(phthalocyaninato)rhodium(III)；Chlororhodium(2+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 14285-57-5
• 化学式: C₃₂H₁₆ClN₈Rh
• 分子量: 650.891
• InChiKey: IPQPQCYHIZXJQT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.81
• 重原子数：
  42
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [ClRh(III)(phthalocyaninate(2-))] 在 potassium cyanide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到potassium dicyano(phthalocyaninato)rhodium(III)
  参考文献：
  名称：

  铑酞菁的循环伏安法和光谱电化学

  摘要：

  通过循环伏安法和UV / VIS光谱电化学研究了含氯化物，吡啶，二甲基亚砜（dmso）和氰化物作为轴向配体的Rh III（pc）（pc =酞菁二价阴离子）配合物的电化学。化合物为K [Rh（pc）（CN）2 ]，[Rh（pc）（Cl）（py）]和[Rh（pc）Cl（dmso）]。对于所有这些，第一氧化发生在酞菁配体上，形成了π-阳离子自由基。取决于轴向配体的性质，将一个电子加到络合物中会产生两种不同的还原产物之一。[Rh（pc）Cl（py）]和[Rh（pc）Cl（dmso）]的首次还原发生在金属上，然后还原物种快速二聚。K [Rh（pc）（CN）2的首次还原]出现在环上。

  DOI：

  10.1039/dt9940001359
• 作为产物：
  描述：

  (phthalocyaninato)Rh(II) 在 HCl 、 O₂ 作用下， 以 not given 为溶剂， 生成 [ClRh(III)(phthalocyaninate(2-))]
  参考文献：
  名称：

  Hanack, Michael, Israel Journal of Chemistry, 1985, vol. 25, p. 205 - 209

  摘要：

  DOI：

文献信息

• The preparation and infra-red spectra of phthalocyanine derivatives of the platinum-group metals
  作者：I.M. Keen、B.W. Malerbi

  DOI：10.1016/0022-1902(65)80095-1

  日期：1965.6

  The i.r. spectra of phthalocyanine derivatives of Pd, Pt, Rh, Ir, Ru, Os in the region 220–5000 cm−1 are reported. The mono (1,2-dicyanobenzene) adducts, PcCl. Ir(III) Cl·C6H4 (CN)2, Pc∗ MCl·C6H4 (CN)2 (MRu(III), Os(III), are found to be the main reaction products of Ir, Ru, Os chlorides and 1,2-dicyanobenzene at ca. 280°C. Osmium tetroxide, OsO4, and 1,2-dicyanobenzene give, at the same reaction

  据报道，Pd，Pt，Rh，Ir，Ru，Os的酞菁衍生物的红外光谱在220–5000 cm -1范围内。单（1,2-二氰基苯）加合物PcCl。发现Ir（III）Cl·C 6 H 4（CN）2，Pc * MCl·C 6 H 4（CN）2（MRu（III），Os（III）是主要的反应产物，Ru，Os氯化物和1,2-二氰基苯在约280°C的温度。四氧化O，OsO 4和1,2-二氰基苯在相同的反应温度下生成（酞菁基）二氧o（VI）-1 ，2-二氰基苯加合物，PcOsO 2 ·C 6 H 4（CN）2。
• Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions
  作者：Didier Villemin、Mohamed Hammadi、Messaoud Hachemi、Nathalie Bar

  DOI：10.3390/61000831

  日期：——

  Metallophthalocyanine complexes are obtained quickly and efficiently by the reaction of phthalodinitrile with hydrated metallic salts without solvent and under microwave irradiation. The use of a modified commercial microwave oven to perform this type of reactions under dry conditions is described. Metallophthalocyanines and metallododecachlorophthalocyanines of some divalent metals can be also obtained

  金属酞菁配合物是通过邻苯二甲腈与水合金属盐在无溶剂和微波辐射下反应快速有效地获得的。描述了使用改进的商用微波炉在干燥条件下进行此类反应。一些二价金属的金属酞菁和金属十二氯酞菁也可以由邻苯二甲酸酐或四氯邻苯二甲酸酐与水合金属盐和尿素在微波辐射和无溶剂条件下制得。
• Dynamics of the triplet state of phthalocyanine complexes of the platinum metals in zero field
  作者：E. R. Menzel、K. E. Rieckhoff、E. M. Voigt

  DOI：10.1063/1.1679197

  日期：1973.6.15

  The luminescence properties of phthalocyanine complexes of platinum metals with d6 and d8 electron configurations were investigated in dilute solutions between room temperature and 1.6°K. For the first time it was possible to study the magnetic sublevels of the triplet state of aromatic molecules in zero field through optical detection methods alone. It was found that the lowest triplet state of these molecules has three zero field components of unequal splitting which depends on the central metal ion and which ranges from approximately 0.1–-10 cm−-1. Intersystem crossing populates solely the highest triplet component which does not radiate to the ground state, but which, in turn, populates the lower lying triplet components. The spin-lattice relaxation rates of these processes could be estimated to be of the order of 105 sec−1 at liquid helium temperature, and the triplet to ground state (S0← T1) decay rates were obtained. A noticeable solvent dependence of the radiationless rates was observed. The effect of spin-orbit coupling and radiationless energy transfer as a function of the metal ion in the phthalocyanine complexes is discussed. Surprisingly, Pd and Rh phthalocyanine were found to fluoresce as well as phosphoresce from essentially ligand-centered,excited states, an unusual occurrence in open d shell transition metal complexes.
• Keen, I. M., 1964, vol. 8, p. 143 - 144
  作者：Keen, I. M.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B2, 2.5.2.2, page 234 - 235
  作者：

  DOI：——

  日期：——