| 92763-12-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 92763-12-7
• 化学式: FeN₆
• 分子量: 139.887
• InChiKey: RYOXVJZSRSCRJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  铁粉 在 N₂ 作用下， 以 gaseous matrix 为溶剂， 生成 iron dinitride 、 Iron;molecular nitrogen 、 、
  参考文献：
  名称：

  Doeff, Marca M.; Parker, Stewart F.; Barrett, Paul H., Inorganic Chemistry, 1984, vol. 23, # 24, p. 4108 - 4110

  摘要：

  DOI：

文献信息

• Binary Iron−Dinitrogen Compounds Synthesized by Co-deposition of Mass-Selected Fe, Fe₂, and Fe₃ with N₂
  作者：T. L. Haslett、S. Fedrigo、K. Bosnick、M. Moskovits、H. A. Duarte、D. Salahub

  DOI：10.1021/ja993911l

  日期：2000.6.1

  Iron-nitrogen binary complexes were synthesized by co-depositing mass-selected Fe+, Fa(2)(+), and Fe-3(+) with N-2 and electrons to form a matrix. The resulting compounds were observed using FTIR spectroscopy. The trigonal-bipyramidal Fe(N-2)(5) structure assigned from the spectra of the Fe+ deposits is supported by density functional calculations involving full geometry optimizations with all symmetry conditions relaxed for Fe(N-2)(x) (x = 1 to 5) binary compounds. FTIR spectra of Fe-2(N-2)(x) and Fe-3(N-2)(y) are also reported. Structures for the dimer and trimer dinitrogen complexes have not been deduced since the spectra are too weak to perform isotopic substitution experiments.