| 913262-87-0

• CAS: 913262-87-0
• 化学式: C₃₆H₃₀O₁₀P₂SSi₂W₂
• 分子量: 1140.51
• InChiKey: XMLMZDBBFLYGPV-SKRAFJHISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  syn-[5,6-dimethyl-2,3-bis(methoxycarbonyl)-7-phenyl-7-phosphanorbornadiene]pentacarbonyltungsten 、 2,5-双[(三甲基硅烷基)乙炔基]噻吩 以 甲苯 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  The Use of Phosphirenes as Conjugating Spacers in Polythiophene Chains

  摘要：

  A series of thienyl-substituted phosphirene P-W(CO)(5) complexes were synthesized by reaction of the transient terminal phosphinidene complex [Ph-P-W(CO)(5)] with the appropriate thienyl-substituted alkynes. The X-ray structural study of these complexes shows coplanar thiophene and phosphirene rings, suggesting a good inter-ring conjugation. A combined C-13 NMR-NBO analysis indicates that the C=C double bond of the phosphirene ring is highly polarizable. UV spectra show a red-shift of the absorption when converting the alkynes into the phosphirenes. CV data are also given.

  DOI：

  10.1021/om060675w