4,34-Dibutoxy-9,14,19,24,26,28,30,32-octamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene | 1236194-80-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4,34-Dibutoxy-9,14,19,24,26,28,30,32-octamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene
• CAS: 1236194-80-1
• 化学式: C₅₁H₆₂O₁₀
• 分子量: 835.047
• InChiKey: NLLGAJOQFMTPRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  61
• 可旋转键数：
  16
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  92.3
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  n-octyltrimethyl ammonium hexafluorophosphate 、 4,34-Dibutoxy-9,14,19,24,26,28,30,32-octamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Syntheses of Copillar[5]arenes by Co-oligomerization of Different Monomers

  摘要：

  Three copillar[5]arenes, pillar[5]arenes containing different repeating units, were successfully prepared by co-oligomerization of different monomers. It was demonstrated that the yields of pillararenes could be improved by using hydroquinone diethers with appropriate aliphatic chain lengths. Pseudorotaxane-type threaded structures were obtained in the solid state by the inclusion of an n-hexane molecule into the cavity of either a homopillar[5]arene, a pillar[5]arene containing only one repeating unit, or a copillar[5]arene.

  DOI：

  10.1021/ol100883k
• 作为产物：
  描述：

  聚合甲醛 、 1,4-二丁氧基苯 、 对苯二甲醚 在 三氟化硼乙醚 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 4.0h， 以16%的产率得到4,34-Dibutoxy-9,14,19,24,26,28,30,32-octamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(26),3(35),4,6(34),8,10,13,15,18(29),19,21(28),23(27),24,30,32-pentadecaene
  参考文献：
  名称：

  Syntheses of Copillar[5]arenes by Co-oligomerization of Different Monomers

  摘要：

  Three copillar[5]arenes, pillar[5]arenes containing different repeating units, were successfully prepared by co-oligomerization of different monomers. It was demonstrated that the yields of pillararenes could be improved by using hydroquinone diethers with appropriate aliphatic chain lengths. Pseudorotaxane-type threaded structures were obtained in the solid state by the inclusion of an n-hexane molecule into the cavity of either a homopillar[5]arene, a pillar[5]arene containing only one repeating unit, or a copillar[5]arene.

  DOI：

  10.1021/ol100883k