Phenanthrene-9,10-di(ethyl carbonate) | 87234-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Phenanthrene-9,10-di(ethyl carbonate)
• 英文别名: (10-Ethoxycarbonyloxyphenanthren-9-yl) ethyl carbonate
• CAS: 87234-41-1
• 化学式: C₂₀H₁₈O₆
• 分子量: 354.359
• InChiKey: JJWXPBVFKGEBEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  氯甲酸乙酯 、 菲醌 在 sodium 作用下， 生成 Phenanthrene-9,10-di(ethyl carbonate)
  参考文献：
  名称：

  Joshi, S. C., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1983, vol. 22, # 5, p. 502 - 503

  摘要：

  DOI：

文献信息

• TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE
  申请人：Coalter, III Joseph N.

  公开号：US20130245306A1

  公开（公告）日：2013-09-19

  A compound suitable for use as an internal electron donor having a structure: wherein R 1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; R 2 is independently at each occurrence, a hydrogen atom or aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; and R3 is an aliphatic hydrocarbyl group having 1 to 3 carbon atoms.

  一种适合用作内电子给体的化合物，其结构为：其中R1在每次出现时独立地为含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；R2在每次出现时独立地为氢原子或含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；而R3为含有1至3个碳原子的脂肪族烃基团。
• JOSHI, S. C., INDIAN J. CHEM., 1983, 22, N 5, 502-503
  作者：JOSHI, S. C.

  DOI：——

  日期：——
• US8263520B2
  申请人：——

  公开号：US8263520B2

  公开（公告）日：2012-09-11
• [EN] TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE<br/>[FR] COMPOSÉS DICARBONATES PONTÉS PAR DEUX ATOMES, COMME DONNEURS INTERNES DANS DES CATALYSEURS POUR LA FABRICATION DE POLYPROPYLÈNE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2011068770A1

  公开（公告）日：2011-06-09

  A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1-O-C(O)-O-]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R1 O C(O)-O- group and a second R1-O-C(O)-O- group.
• Joshi, S. C., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1983, vol. 22, # 5, p. 502 - 503
  作者：Joshi, S. C.

  DOI：——

  日期：——