dibromocopper;1-[di(pyrazol-1-yl)methyl]pyrazole | 95053-70-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: dibromocopper;1-[di(pyrazol-1-yl)methyl]pyrazole
• CAS: 95053-70-6
• 化学式: C₁₀H₁₀Br₂CuN₆
• 分子量: 437.584
• InChiKey: PHXYDMNGEOETLM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三(吡唑)甲烷 、 copper(ll) bromide 以 甲醇 为溶剂， 以56%的产率得到dibromocopper;1-[di(pyrazol-1-yl)methyl]pyrazole
  参考文献：
  名称：

  Synthesis, spectroscopic and structural characterization of Cu(II) derivatives of tris(pyrazol-1-yl)methanes

  摘要：

  The reaction between CuX2 (X = ClO4, NO3, Cl, Br and CH3COO) and excess of tris(pyrazol-1-yl)methane ligands L (L = CH(pz)(3). CH(4-Mepz)(3), CH(3,5-Me(2)pz)(3), CH(3,4,5-Me(3)pz)(3) or CH(3-Mepz)(2)(5-Mepz)) yields [CuX2(L)], [{CuX2}(3)(L-2)(2)] or [Cu(L-2)]X-2-type complexes. The ligand to metal ratio is dependent on the number and disposition of the Me substituents on the azole-type ligand and mainly on the nature of the counter-ion X. All complexes have been characterized in the solid state as well as in solution (IR and UV spectra, and conductivity determinations). The solid-state structures of [Cu{(3,5-Me(2)pz)(3)CH}(2)](NO3)(2), [Cu{(3,5-Me(2)pz)(3)CH}(2)](ClO4)(2).0.5H(2)O, [Cu{(3,4,5-Me(3)pz)(3)CH}(2)](NO3)(2).H2O, [Cu{(4-Mepz)(3)CH}(2)]Br-2.3H(2)O have been determined by single crystal X-ray studies. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00772-7