| 146190-76-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯二氮卓类
• CAS: 146190-76-3
• 化学式: C₃₅H₃₈N₄NiO₂
• 分子量: 605.402
• InChiKey: WZRIOUCLLDZZHN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 2,2-Bis-cyclohexylmethyl-N,N'-di-quinolin-8-yl-malonamide 以 乙醇 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Role of substituents in copper(II) extraction with N,N′-bis(8-quinolyl)malonamides

  摘要：

  It has been found that substituents on N,N'-bis(8-quinolyl)malonamide play an important role in copper(II) extraction: among the substituents studied, benzyl groups dramatically increased extractability of the malonamide complex. The role of substituents is discussed on the basis of the results of titration and H-1 NMR measurements of copper(II) or nickel(II) complexes as well as copper(II)-extraction experiments. Intramolecular interactions between pi electrons of the benzyl group and the metal centre of the complex are proposed to occur.

  DOI：

  10.1039/dt9920002679