Co(5-phenyloctaethylporphyrin) | 439601-50-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Co(5-phenyloctaethylporphyrin)
• CAS: 439601-50-0
• 化学式: C₄₂H₄₈CoN₄
• 分子量: 667.863
• InChiKey: HBFPXBGKROIUJU-YMTASMNGSA-N

反应信息

• 作为反应物：
  描述：

  Co(5-phenyloctaethylporphyrin) 在 三氟乙酸 作用下， 以 溶剂黄146 为溶剂， 生成 2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrine
  参考文献：
  名称：

  摘要：

  The dissociation kinetics of the cobalt and copper complexes with octaethylporphyrin, its 5-phenyl, 5,15-diphenyl, and 5,10,15,20-tetraphenyl derivatives, and dodecaphenylporphyrin in acetic acid with small additions of trifluoroacetic acid were studied. In this series of complexes, the steric distortion of the tetrapyrrole macrocycle sequentially increases, which results in a regular decrease in the kinetic stability of the metal porphyrins: The dissociation rate increases by three orders of magnitude.

  DOI：

  10.1023/a:1015322118490
• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrine 在 cobalt(II) acetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 Co(5-phenyloctaethylporphyrin)
  参考文献：
  名称：

  摘要：

  The dissociation kinetics of the cobalt and copper complexes with octaethylporphyrin, its 5-phenyl, 5,15-diphenyl, and 5,10,15,20-tetraphenyl derivatives, and dodecaphenylporphyrin in acetic acid with small additions of trifluoroacetic acid were studied. In this series of complexes, the steric distortion of the tetrapyrrole macrocycle sequentially increases, which results in a regular decrease in the kinetic stability of the metal porphyrins: The dissociation rate increases by three orders of magnitude.

  DOI：

  10.1023/a:1015322118490

文献信息

• ——
  作者：E. M. Kuvshinova、D. L. Kuz'min、S. G. Pukhovskaya、A. S. Semeikin、O. A. Golubchikov

  DOI：10.1023/a:1025673427341

  日期：——

  Octaethyl-, 5-phenyloctaethyl-, 5,15-diphenyloctaethyl-, 5,10,15,20-tetraphenyloctaethyl, and dodecaphenylporphyrins were prepared, and their geometries were optimized by the method of molecular mechanics. The deformation of the porphyrin macroring grows as the number of phenyl groups is increased. The dissociation kinetics of the manganese, cobalt, and copper complexes of the porphyrins in solutions of sulfuric acid in acetic acid were studied. The kinetic parameters of the dissociation of metal porphyrins were analyzed in relation to the porphyrin structure and nature of the metal.