1,1-Bis-tert.-butylperoxy-propan | 39222-17-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 1,1-Bis-tert.-butylperoxy-propan
• 英文别名: 1,1-Di-tert.-butyl-peroxypropan；di-tert-butyl propane-1,1-diyl bis-peroxide；2-(1-Tert-butylperoxypropylperoxy)-2-methylpropane
• CAS: 39222-17-8
• 化学式: C₁₁H₂₄O₄
• 分子量: 220.309
• InChiKey: WWRKZSZVRWMQRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,1-Bis-tert.-butylperoxy-propan 生成
  参考文献：
  名称：

  Shreibert,A.I. et al., Journal of general chemistry of the USSR, 1972, vol. 42, p. 1855

  摘要：

  DOI：
• 作为产物：
  描述：

  叔丁基过氧化氢 、 丙醛 生成 1,1-Bis-tert.-butylperoxy-propan
  参考文献：
  名称：

  Rieche,A. et al., Chemische Berichte, 1961, vol. 94, p. 2932 - 2936

  摘要：

  DOI：

文献信息

• 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
  申请人：——

  公开号：US20030065184A1

  公开（公告）日：2003-04-03

  The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

  本发明涉及选择的1-烷氧基-2,2-二乙基-6,6-二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物，这些衍生物在4位被氧或氮原子取代；包括a）至少一种乙烯基不饱和单体和b）所述哌啶衍生物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的过程，以及使用在4位被氧或氮原子取代的1-烷氧基-2,2-二乙基-6,6-二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物进行受控聚合。中间体N-氧基衍生物，N-氧基衍生物与乙烯基不饱和单体和自由基引发剂的组合物，以及聚合的过程也是本发明的主题。
• N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
  申请人：Nesvadba Peter

  公开号：US20060149011A1

  公开（公告）日：2006-07-06

  The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

  本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成开链或环状璃缩酮结构，包括a）至少一种乙烯基不饱和单体和b）所述哌啶衍生物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶、1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成开链或环状璃缩酮结构，用于受控聚合。中间体N-氧基衍生物，N-氧基衍生物与乙烯基不饱和单体和自由基引发剂的组合物，以及聚合方法也是本发明的对象。
• Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
  申请人：Hintermann Tobias

  公开号：US20050124814A1

  公开（公告）日：2005-06-09

  The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.

  本发明涉及开链烷氧胺化合物，一种可聚合组合物，包括a)至少一种乙烯基不饱和单体和b)至少一种开链烷氧胺化合物。本发明的进一步方面包括聚合乙烯基不饱和单体的过程，以及使用开链烷氧胺化合物进行控制聚合。中间体N-氧化物衍生物，N-氧化物衍生物与乙烯基不饱和单体和自由基引发剂X的组合物，以及用于聚合的过程和它们的使用也是本发明的主题。
• 1-Alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
  申请人：Kramer Andreas

  公开号：US20050131177A1

  公开（公告）日：2005-06-16

  The present invention relates to 1-alkoxy-polyalkyipiperidine derivatives containing a structural element of formula (I) G 1 , G 2 , G 3 , G 4 are Independently C 1 -C 6 alkyl with the proviso that at least one is not methyl or G 1 and G 2 or G 3 and G 4 , or G 1 and G 2 and G 3 and G 4 together form a C 5 -C 12 cycloalkyl group; G 5 , G 6 independently are H, C 1 -C 18 alkyl, phenyl, naphthyl or a group COOC 1 -C 18 alkyl and X represents a group such that the free radical Xe derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X•, as well as a process for polymerization are also subjects of the present invention.

  本发明涉及一种含有结构元素公式（I）的1-烷氧基-多烷基哌啶衍生物，其中G1、G2、G3、G4独立地为C1-C6烷基，但至少有一个不是甲基，或者G1和G2或G3和G4，或者G1、G2、G3和G4共同形成一个C5-C12环烷基；G5、G6独立地为H、C1-C18烷基、苯基、萘基或COOC1-C18烷基，X代表一种基团，使得来自X的自由基Xe能够引发乙烯基不饱和单体的聚合，但化合物A1和A2被排除在外。本发明的另外几个方面包括：包括a）至少一种乙烯基不饱和单体和b）一种1-烷氧基-多烷基哌啶衍生物的可聚合组合物、聚合乙烯基不饱和单体的方法，以及使用1-烷氧基-多烷基哌啶衍生物进行控制聚合。本发明的中间体N-氧基衍生物、N-氧基衍生物与乙烯基不饱和单体和自由基引发剂X•的组合物，以及聚合的方法也是本发明的内容。
• Process for the preparation of hydroxy-vinyl-aromatic polymers or copolymers by anionic or controlled radical polymerization
  申请人：——

  公开号：US20040242813A1

  公开（公告）日：2004-12-02

  The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed in a hydrogenation process. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.

  本发明涉及一种制备羟基乙烯基芳香聚合物，特别是4-羟基苯乙烯聚合物或共聚物的方法，该方法通过阴离子或受控自由基聚合制备相应的单体，其中羟基功能基被保护基阻断，随后在氢化过程中去除保护基。所得到的（共）聚合物具有狭窄的聚分散度，适用于制造光刻胶。