| 1443616-51-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 1443616-51-0
• 化学式: C₇₂H₈₆N₆O₄S₁₆
• 分子量: 1612.57
• InChiKey: UGBCEZMXFSVDQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.63
• 重原子数：
  98.0
• 可旋转键数：
  20.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  120.34
• 氢给体数：
  2.0
• 氢受体数：
  26.0

反应信息

• 作为产物：
  描述：

  2-(2-azidoethylthio)-6,7-bis(methylthio)-3-methylthiotetrathiafulvalene 、 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-dipropargylcalix[4]arene 在 copper(ll) sulfate pentahydrate 、 sodium ascorbate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以32%的产率得到
  参考文献：
  名称：

  Novel clicked tetrathiafulvalene-calix[4]arene assemblies: Synthesis and intermolecular electron transfer toward p-chloranil

  摘要：

  Two tetrathiafulvalene-calix[4]arene assemblies (TTF-calix-1 and TTF-calix-2) have been synthesized by the click reaction. Both their cyclic voltammograms show, as expected, two one-electron quasi-reversible redox behavior. The UV-vis absorption spectra studies show that these two assemblies undergo progressive oxidation at the TTF moiety in presence of increasing amounts of Cu2+ or Hg2+. Moreover, the absorption studies show intermolecular electron transfer between compounds TTF-calix-1 or TTF-calix-2 and p-chloranil may be promoted by specific metal ions such as Pb2+, Sc3+ etc. (c) 2013 Bang-Tun Zhao and Wei-Min Zhu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.04.026