[4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophene-2-carboxylate | 499204-92-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophene-2-carboxylate
• CAS: 499204-92-1
• 化学式: C₃₆H₂₃F₆NO₅S₂
• 分子量: 727.705
• InChiKey: XWYFPUCBBZJTER-GQYOUUAKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  50
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophene-2-carboxylate 以 四氢呋喃 为溶剂， 反应 0.01h， 生成 4,4,5,5,6,6-Hexafluoro-9a,9b-dimethyl-8-phenyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene-2-carboxylic acid 4-((1R,2S,6R,7S)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939
• 作为产物：
  描述：

  全氟环戊烯 在 正丁基锂 、 草酰氯 、 叔丁基锂 、 三乙胺 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 二氯甲烷 、 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 2.17h， 生成 [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[3,3,4,4,5,5-hexafluoro-2-(2-methyl-5-phenylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophene-2-carboxylate
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939

文献信息

• Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ma0211939

  日期：2003.1.1

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.