9-(4-hydroxyphenyl)-3,6-dimethylcarbazole | 1147131-33-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(4-hydroxyphenyl)-3,6-dimethylcarbazole
• 英文别名: 3,6-dimethyl-9-(4-hydroxyphenyl)carbazole；4-(3,6-dimethylcarbazol-9-yl)phenol
• CAS: 1147131-33-6
• 化学式: C₂₀H₁₇NO
• 分子量: 287.361
• InChiKey: UVFUDVMDHQVBAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  25.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,9'-(6-氯-1,3,5-三嗪-2,4-二基)双(9H-咔唑) 、 9-(4-hydroxyphenyl)-3,6-dimethylcarbazole 在 sodium hydroxide 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 8.17h， 以80%的产率得到9-[4-[[4,6-Di(carbazol-9-yl)-1,3,5-triazin-2-yl]oxy]phenyl]-3,6-dimethylcarbazole
  参考文献：
  名称：

  Designing a bipolar host material for blue phosphorescent OLEDs: Phenoxy-carbazole substituted triazine

  摘要：

  A novel phenoxy-carbazole substituted triazine host material (PCTrz) was synthesised. PCTrz exhibits a high triplet bandgap of 2.91 eV and a high glass transition temperature of 148 degrees C. A non-conjugated ether bond separates the oxidation-and reduction-site in the molecule. Good charge carrier transport properties in single carrier devices prove the potential as host for blue phosphorescent emitters. An organic light emitting diode with PCTrz as host for FIrpic exhibited a high current efficiency of 13.5 cd/A a luminance of 1000 cd/m(2) and a maximum luminance of 29,000 cd/m(2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2011.03.038
• 作为产物：
  描述：

  3,6-二甲基-9H-咔唑 在 potassium phosphate 、 copper(l) iodide 、 三溴化硼 、 trans-1,2-cyclohexanediamine 作用下， 以 1,4-二氧六环 、 二氯甲烷 为溶剂， 反应 26.0h， 生成 9-(4-hydroxyphenyl)-3,6-dimethylcarbazole
  参考文献：
  名称：

  Designing a bipolar host material for blue phosphorescent OLEDs: Phenoxy-carbazole substituted triazine

  摘要：

  A novel phenoxy-carbazole substituted triazine host material (PCTrz) was synthesised. PCTrz exhibits a high triplet bandgap of 2.91 eV and a high glass transition temperature of 148 degrees C. A non-conjugated ether bond separates the oxidation-and reduction-site in the molecule. Good charge carrier transport properties in single carrier devices prove the potential as host for blue phosphorescent emitters. An organic light emitting diode with PCTrz as host for FIrpic exhibited a high current efficiency of 13.5 cd/A a luminance of 1000 cd/m(2) and a maximum luminance of 29,000 cd/m(2). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2011.03.038

文献信息

• USE OF DIPHENYLAMINO-BIS(PHENOXY)- AND BIS(DIPHENYLAMINO)-PHENOXYTRIAZINE COMPOUNDS
  申请人：Fuchs Evelyn

  公开号：US20100258790A1

  公开（公告）日：2010-10-14

  The present invention relates to an organic light-emitting diode comprising at least one diphenylaminobis(phenoxy)triazine or at least one bis(diphenylamino)phenoxytriazine compound, to a light-emitting layer comprising at least one diphenylamino-bis(phenoxy)triazine or at least one bis(diphenylamino)phenoxytriazine compound, to the use of the aforementioned compounds as a matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode.

  本发明涉及一种有机发光二极管，包括至少一种二苯胺基双(苯氧基)三嗪或至少一种双(二苯胺基)苯氧基三嗪化合物，以及包括至少一种二苯胺基双(苯氧基)三嗪或至少一种双(二苯胺基)苯氧基三嗪化合物的发光层，以及上述化合物作为基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴导体材料和/或电子导体材料的用途，以及从固定式视觉显示单元、移动式视觉显示单元和至少包括一种创新的有机发光二极管的照明单元中选择的装置。
• Designing a bipolar host material for blue phosphorescent OLEDs: Phenoxy-carbazole substituted triazine
  作者：Michael M. Rothmann、Evelyn Fuchs、Christian Schildknecht、Nicolle Langer、Christian Lennartz、Ingo Münster、Peter Strohriegl

  DOI：10.1016/j.orgel.2011.03.038

  日期：2011.7

  A novel phenoxy-carbazole substituted triazine host material (PCTrz) was synthesised. PCTrz exhibits a high triplet bandgap of 2.91 eV and a high glass transition temperature of 148 degrees C. A non-conjugated ether bond separates the oxidation-and reduction-site in the molecule. Good charge carrier transport properties in single carrier devices prove the potential as host for blue phosphorescent emitters. An organic light emitting diode with PCTrz as host for FIrpic exhibited a high current efficiency of 13.5 cd/A a luminance of 1000 cd/m(2) and a maximum luminance of 29,000 cd/m(2). (C) 2011 Elsevier B.V. All rights reserved.