Benzophenanthro<4,3-d>thiophene | 192-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Benzophenanthro<4,3-d>thiophene
• 英文别名: Benzo[b]phenanthro[4,3-d]thiophene；2-(3,4-Dibromophenyl)pyridine；9-thiapentacyclo[11.8.0.02,10.03,8.016,21]henicosa-1(13),2(10),3,5,7,11,14,16,18,20-decaene
• CAS: 192-88-1
• 化学式: C₂₀H₁₂S
• 分子量: 284.381
• InChiKey: MNZURLNXWRFPND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-(Benzothiophen-2-yl)-2-(2'-naphthyl)ethene 在 碘 作用下， 以 环己烷 为溶剂， 反应 4.0h， 以25%的产率得到Benzophenanthro<4,3-d>thiophene
  参考文献：
  名称：

  Pratap, Ram; Lee, Milton L.; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1982, vol. 19, p. 219 - 220

  摘要：

  DOI：

文献信息

• NOVEL ORGANIC HETEROCYCLIC COMPOUND AND LIGHT-EMITTING DEVICE COMPRISING SAME
  申请人：SFC CO., LTD.

  公开号：US20180072753A1

  公开（公告）日：2018-03-15

  The present invention relates to an organic light-emitting compound represented by [Chemical Formula A] and an organic light-emitting device. In Chemical Formula, A, X, Y, Z, and the substituents R 1 to R 8 , and R 11 to R 20 are as defined in the specification.

  本发明涉及一种由[化学公式A]表示的有机发光化合物以及一种有机发光器件。在化学公式中，A、X、Y、Z以及取代基R1至R8和R11至R20如说明书中所定义。
• Exploiting the π-Acceptor Properties of Carbene-Stabilized Phosphorus Centered Trications [L₃P] ³⁺: Applications in Pt(II) Catalysis
  作者：Javier Carreras、Mahendra Patil、Walter Thiel、Manuel Alcarazo

  DOI：10.1021/ja306947m

  日期：2012.10.10

  Reaction of tris(dimethylaminocyclopropenium) substituted phosphine 1 with K2PtCl4 afforded the bench stable complex 3 which upon treatment with Ag[CB11H6Cl6] turned out to be an excellent catalyst for the transformation of a variety of ortho-biaryl substituted alkynes into polycyclic homo- and heteroarenes of different size, shape, and curvature through a 6-endo-dig cyclization. This constitutes the first example ever reported of using a P-1-centered trication as ligand in catalysis. The strong pi-acceptor character of 1 that derives from its three positive charges substantially increases the intrinsic pi-acidity of Pt in complex 1.PtCl2 and dramatically enhances its ability to activate pi-systems toward nucleophilic attack. As a consequence, a remarkable acceleration of the model transformation is observed when compared with other classical pi-acceptor ligands such as P(OPh)(3) or P(C6F5)(3). Moreover, the employment of 1 as ligand also expands the scope of this reaction to previously inaccessible substitution patterns. Kinetic studies and deuterium labeling experiments as well as density functional theory (DFT) calculations were performed in order to explain these findings.
• Tedjamulia, Marvin L.; Tominaga, Yoshinori; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1983, vol. 20, p. 861 - 866
  作者：Tedjamulia, Marvin L.、Tominaga, Yoshinori、Castle, Raymond N.、Lee, Milton L.

  DOI：——

  日期：——
• PRATAP, RAM;LEE, M. L.;CASTLE, R. N., J. HETEROCYCL. CHEM., 1982, 19, N 1, 219-220
  作者：PRATAP, RAM、LEE, M. L.、CASTLE, R. N.

  DOI：——

  日期：——
• TEDJAMULIA, M. L.;TOMINAGA, YOSHINORI;CASTLE, R. N.;LEE, M. L., J. HETEROCYCL. CHEM., 1983, 20, N 4, 861-866
  作者：TEDJAMULIA, M. L.、TOMINAGA, YOSHINORI、CASTLE, R. N.、LEE, M. L.

  DOI：——

  日期：——