9,10-dibutyl-9,10-dihydro-9,10-phenanthrenediol | 844700-76-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,10-dibutyl-9,10-dihydro-9,10-phenanthrenediol
• 英文别名: 9,10-dibutyl-9,10-dihydro-phenanthrene-9,10-diol；9.10-Dihydroxy-9.10-dibutyl-9.10-dihydro-phenanthren；9,10-Dibutyl-9,10-dihydro-phenanthren-9,10-diol；9,10-Dibutyl-9,10-dihydrophenanthrene-9,10-diol；9,10-dibutylphenanthrene-9,10-diol
• CAS: 844700-76-1
• 化学式: C₂₂H₂₈O₂
• 分子量: 324.463
• InChiKey: YEFAVMJBTPZZBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-dibutyl-9,10-dihydro-9,10-phenanthrenediol 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 lithium aluminium tetrahydride 、 四(三苯基膦)钯 、 甲烷磺酸 、 溴 、 碘 、 potassium acetate 、 sodium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 四氯化碳 、 乙二醇二甲醚 、 二氯甲烷 、 水 为溶剂， 反应 15.58h， 生成
  参考文献：
  名称：

  Scholl 反应中的区域选择性：单和双 [7] 螺旋

  摘要：

  我们采用了密度泛函理论 (DFT) 预测的菲和二苯并 [ g , p ] 骨架中分子内 Scholl 反应的区域选择性，分别获得了 π 扩展的单和双 [7] 螺旋。尽管与其最稳定的异构体相比，积累了高达 30 kcal/mol 的大应变能，但仍会形成这些螺旋结构。通过实验（核磁共振、紫外-可见光、发射、电化学和单晶 X 射线衍射）技术对扭曲和应变结构进行了表征和分析，并得到了 DFT 计算的进一步支持。

  DOI：

  10.1021/acs.orglett.1c01706
• 作为产物：
  描述：

  2,2'-Divaleryl-biphenyl 在 水 、 zinc(II) chloride 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以96%的产率得到9,10-dibutyl-9,10-dihydro-9,10-phenanthrenediol
  参考文献：
  名称：

  Scholl 反应中的区域选择性：单和双 [7] 螺旋

  摘要：

  我们采用了密度泛函理论 (DFT) 预测的菲和二苯并 [ g , p ] 骨架中分子内 Scholl 反应的区域选择性，分别获得了 π 扩展的单和双 [7] 螺旋。尽管与其最稳定的异构体相比，积累了高达 30 kcal/mol 的大应变能，但仍会形成这些螺旋结构。通过实验（核磁共振、紫外-可见光、发射、电化学和单晶 X 射线衍射）技术对扭曲和应变结构进行了表征和分析，并得到了 DFT 计算的进一步支持。

  DOI：

  10.1021/acs.orglett.1c01706

文献信息

• Conjugated polymers containing dihydrophenanthrene units and use thereof
  申请人：Becker Heinrich

  公开号：US20070060736A1

  公开（公告）日：2007-03-15

  The invention relates to conjugated polymers containing novel structural units according to formula (1). The inventive materials are characterized by increased efficiency and a longer service life when used in polymer organic light emitting diodes. The present invention relates to conjugated polymers which comprise novel structural units of the formula (I). The materials of the invention display improved efficiency and a longer life when used in polymeric organic light-emitting diodes.

  本发明涉及具有新结构单元的共轭聚合物，其化学式为（1）。这种创新材料在聚合物有机发光二极管中使用时具有更高的效率和更长的使用寿命。本发明涉及包含化学式（I）的新型结构单元的共轭聚合物。该发明的材料在聚合物有机发光二极管中使用时具有改善的效率和更长的寿命。
• Chu; Shen, Journal of the Chinese Chemical Society (Peking), 1943, vol. 10, p. 116
  作者：Chu、Shen

  DOI：——

  日期：——
• Jezierski; Spotowska, Roczniki Chemii, 1934, vol. 14, p. 1243,1245
  作者：Jezierski、Spotowska

  DOI：——

  日期：——
• Child and Adolescent Sexual Abuse History in a Sample of 1,490 Women Sexual Partners of Injection Drug-Using Men
  作者：Robert C. Freeman、Kathleen M. Parillo、Karyn Collier、Ryan W. Rusek

  DOI：10.1300/j013v34n04_03

  日期：2001.12.13

  Subjects for this study were 1490 community-recruited women sexual partners of injection drug-using men who were interviewed in three U.S. cities during 1990-'92. Data were collected on respondents' childhood and adolescent sexual abuse history, identity of abuse perpetrators and duration of abuse. Over 56 percent of respondents reported a history of sexual victimization by age 18, including 39 percent who were abused before age 12 and over 53 percent who were victimized by abuse involving bodily contact by age 18. One in three women were victimized by unwanted penetration by age 18. White women more likely than African-American and Hispanic women to have been the victims of virtually every type of abusive act investigated here. Overall, nearly two out of three White women had experienced some form of sexual abuse by age 18, including almost 42 percent who were the victims of unwanted penetration by this age. Acts of forced sexual touching and penetration occurring in childhood were most likely to have been carried out by an uncle or other relative of the victim; family members were much less likely to be the perpetrators of adolescent contact abuse. Based on these findings, it appears that many in this special population of women are likely to be at substantial risk for some of the long-term effects of early life sexual abuse, including those that may reduce victims' ability to take preventive action against HIV risk. Recommendations are offered for those who function as caregivers to this population, including drug treatment personnel. (C) 2001 by The Haworth Press, Inc. All rights reserved.
• KONJUGIERTE POLYMERE ENTHALTEND DIHYDROPHENANTHREN-EINHEITEN UND DEREN VERWENDUNG
  申请人：Covion Organic Semiconductors GmbH

  公开号：EP1656408A2

  公开（公告）日：2006-05-17