[Zinc(II)(5-(1-methyl-2-imidazolyl)-10,20-bis(2-methoxy-carbonyl-ethyl)phorphyrin-2H)(pyridine)] | 911417-00-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Zinc(II)(5-(1-methyl-2-imidazolyl)-10,20-bis(2-methoxy-carbonyl-ethyl)phorphyrin-2H)(pyridine)]
• CAS: 911417-00-0
• 化学式: C₃₇H₃₃N₇O₄Zn
• 分子量: 705.104
• InChiKey: PMDBUXFRFBSNJE-YTBFAABFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 [Zinc(II)(5-(1-methyl-2-imidazolyl)-10,20-bis(2-methoxy-carbonyl-ethyl)phorphyrin-2H)]2 以 氯仿 为溶剂， 生成 [Zinc(II)(5-(1-methyl-2-imidazolyl)-10,20-bis(2-methoxy-carbonyl-ethyl)phorphyrin-2H)(pyridine)]
  参考文献：
  名称：

  Nonlinear Absorption and Nonlinear Refraction of Self-Assembled Porphyrins

  摘要：

  Nonlinear refraction and nonlinear absorption of self-assembled porphyrins in the nanosecond and picosecond regimes were studied at 532 nm by the Z-scan technique. First, a marked difference in nonlinear refraction was observed between self-assembled zinc porphyrins and free base porphyrins; however, the effects of self-assembly and metallization on nonlinear absorption are small. Second, an enhancement of nonlinear absorption was observed for the monomeric components of self-assembled structures by adding pyridine, while their nonlinear refractions remained almost unchanged as pyridine was added. It is expected that the metallization and addition of ligand can provide more convenient routes to alter the optical nonlinearities of porphyrins than the modifications of molecular structures of traditional covalent-bond organic materials.

  DOI：

  10.1021/jp061799p