[Cu(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)2Br2] | 663606-61-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Cu(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)2Br2]
• 英文别名: dibromocopper;N-[(E)-(1,5-dimethyl-3-oxo-2-phenylpyrazol-4-yl)methylideneamino]benzamide
• CAS: 663606-61-9
• 化学式: C₃₈H₃₆Br₂CuN₈O₄
• 分子量: 892.109
• InChiKey: IHRQVOJINBDYIB-APYLNELOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 1,2-dihydro-1,5-dimethyl-2-phenyl-4-formyl(benzhydrazide)-3H-pyrazol-3-one 以 乙腈 为溶剂， 以84%的产率得到[Cu(2,3-dimethyl-4-formyl(benzhydrazide)-1-phenyl-3-pyrazolin-5-one)2Br2]
  参考文献：
  名称：

  Complexes of Copper(II) with 2,3‐Dimethyl‐4‐formyl(benzhydrazide)‐1‐phenyl‐3‐pyrazolin‐5‐one

  摘要：

  Copper(H) complexes of the Schiff base 2,3-dimethyl-4-formyl-(benzhydrazide)-1-phenyl-3-pyrazolin-5-one (L) of the general formula [Cu(L)(2)]X-2 (X = ClO4 or NO3), [Cu(L)Cl-2] and [Cu(L)(2)Br-2] have been synthesized and characterized by elemental analyses, electrical conductance in non-aqueous solvents, infrared, electronic and EPR spectra, as well as magnetic susceptibility measurements. fit these complexes, the ligand acts as a neutral bidentate unit coordinating through the azomethine nitrogen atom and the carbonyl oxygen of the pyrazolone ring. In the perchlorate and nitrate complexes both anions remain ionic, while in the corresponding halide complexes both anions are coordinated to the metal ion. The perchlorate, nitrate and chloride complexes are of square-planar Geometry while the bromide complex is of distorted octahedral geometry.

  DOI：

  10.1081/sim-120024311