((2,6-diisopropylphenylimino)methyl)pyrazine | 215459-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((2,6-diisopropylphenylimino)methyl)pyrazine
• 英文别名: N-(2,6-diisopropylphenyl)pyrazin-2-ylmethanimine；N-[2,6-di(propan-2-yl)phenyl]-1-pyrazin-2-ylmethanimine
• CAS: 215459-03-3
• 化学式: C₁₇H₂₁N₃
• 分子量: 267.374
• InChiKey: BZOMVWGWRIIBCX-UHFFFAOYSA-N

物化性质

• 沸点：
  434.6±45.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  38.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  ((2,6-diisopropylphenylimino)methyl)pyrazine 在 甲醇 、 sodium tetrahydroborate 作用下， 以98%的产率得到2,6-di(propan-2-yl)-N-(pyrazin-2-ylmethyl)aniline
  参考文献：
  名称：

  BIDENTATE DIAZINYLAMIDO COMPLEXES AS CATALYSTS FOR OLEFIN POLYMERIZATION

  摘要：

  本公开的实施例包括催化剂系统，该系统包括符合公式(I)的金属配体复合物。

  公开号：

  US20220227904A1
• 作为产物：
  描述：

  2,6-二异丙基苯胺 、 2-吡嗪甲醛 以 甲醇 为溶剂， 反应 24.0h， 以28%的产率得到((2,6-diisopropylphenylimino)methyl)pyrazine
  参考文献：
  名称：

  BIDENTATE DIAZINYLAMIDO COMPLEXES AS CATALYSTS FOR OLEFIN POLYMERIZATION

  摘要：

  本公开的实施例包括催化剂系统，该系统包括符合公式(I)的金属配体复合物。

  公开号：

  US20220227904A1

文献信息

• Tandem pinacol coupling–rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate
  作者：Olena Branytska、Linda J. W. Shimon、Ronny Neumann

  DOI：10.1039/b710100g

  日期：——

  Together with a strongly oxidizing polyoxometalate, H5PV2Mo10O40, PtII(N-(2,6-diisopropylphenyl)pyrazin-2-ylmethanimine)Cl2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

  一种强氧化性的多金属氧酸盐H5PV2Mo10O40与PtII(N-(2,6-二异丙基苯基)吡嗪-2-亚甲亚胺)Cl2组成的复合催化剂，在以分子氢为还原剂的条件下，对芳基醛的联苯偶联-重排反应展现出活性，能够高产率地得到相应的二芳基乙二醛。
• The role of bulky substituents in the polymerization of ethylene using late transition metal catalysts: a comparative study of nickel and iron catalyst systems
  作者：George J.P Britovsek、Simon P.D Baugh、Olivier Hoarau、Vernon C Gibson、Duncan F Wass、Andrew J.P White、David J Williams

  DOI：10.1016/s0020-1693(02)01293-8

  日期：2003.3

  A series of nickel(II) and iron(II) complexes of the general formula [LMX2] containing bidentate (for M = Ni) and tridentate (for M = Fe) heterocycle-imine ligands L have been synthesized and characterized. Compared to the well-known alpha-diimine nickel and bis(imino)pyridine iron catalysts, these systems contain a bulky imine substituent on one side and a non-bulky N-heterocycle on the other. Depending on the ligand and the conditions used, either four- or five-coordinate complexes are obtained in the case of nickel. Iron complexes are generally five-coordinate, even with potentially tetradentate ligands. Activation of these precatalysts with MAO affords active catalyst systems for the oligomerization/polymerization of ethylene. Compared to alpha-diimine nickel and bis(imino)pyridine iron catalysts, both- metal systems provide only half of the steric protection and consequently the catalytic activities and the degree of polymerization are significantly lower. Lower activities are attributed to a reduced stability of the active species under polymerization conditions, whereas the lower molecular weights are a result of increased beta-H transfer rates. Variations within the heterocyclic component of the ligand reveal that both steric and electronic factors influence the polymerization behavior of these catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.
• BIDENTATE DIAZINYLAMIDO COMPLEXES AS CATALYSTS FOR OLEFIN POLYMERIZATION
  申请人：Dow Global Technologies LLC

  公开号：US20220227904A1

  公开（公告）日：2022-07-21

  Embodiments of this disclosure include catalyst systems comprising a metal-ligand complex according to formula (I):

  本公开的实施例包括催化剂系统，该系统包括符合公式(I)的金属配体复合物。