tetrakis(salicylaldehydato)zirconium(IV) | 65531-97-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: tetrakis(salicylaldehydato)zirconium(IV)
• 英文别名: tetrakis(salicylaldhydato)zirconium(IV)
• CAS: 65531-97-7
• 化学式: C₂₈H₂₀O₈Zr
• 分子量: 575.686
• InChiKey: HRHKMRZWBOMEOV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tetrakis(salicylaldehydato)zirconium(IV) 、 N,N'-bis-(5-tert-butylasalicylidene)-1,2-phenylenediamine 以 氘代二甲亚砜 为溶剂， 生成 bis[N,N'-bis-(5-tert-butylsalicylidene)-1,2-diaminobenzenato]zirconium(IV)
  参考文献：
  名称：

  Eight-coordinate Schiff-base zirconium polymers: synthesis, characterization and properties

  摘要：

  The condensation polymerization of tetrakis (salicylaldhydato) zirconium(IV) (Zr(sal)(4)) and 3,3',4,4'-tetraaminodiphenylmethane, produces the polymer catena-poly [zirconium(IV) (mu-N,N',N '',N'''-tetrasalicylidene-3,3',4,4'-tetraaminobiphenylmethanato-O,N',N',O':-O '',N '',N'''O''')] ([Zr(tstm>](n)), with a number-average molecular mass <(M)over bar (n)>, above 13000 based on gel permeation chromatography and nuclear magnetic resonance end-group evaluations. Reaction of Zr(sal)(4) with 3,3',4,4'-tetraaminodiphenylsulfone yields catena-poly-[zirconium(IV) (mu-N,N',N '', N'''-tetrasalicylidene-3,3',4,4'-tetraaminobiphenylsulfonato-O,N,N',O':O '', N '',N''',O''')] ([Zr(tsts)](n)) with M(n) above 8700. The polymers show thermal stability above 400 degrees C in air. Films of these polymers and catena-poly [zirconium(IV) (mu-N,N',N '',N'''-tetrasalicylidene-3,3'-diaminobenzinato-O.N,N',O:O '',N '',N '',O''')] ([Zr(tsdb)](n)) and the cerium(IV) analogs, [Ce(tsdb)](n), [Ce(tstm)](n) and [Ce(tsts)](n) cast on chrome-plated steel were found to be continuous by scanning electron microscopy, and they have conductivities on glass of similar to 10(-7) S cm(-1) (increased by a factor of similar to 10(4) by I-2 doping).

  DOI：

  10.1016/s0020-1693(96)05255-3
• 作为产物：
  描述：

  (monochloro)oxozirconium(IV) 2-chlorophenoxide 、 水杨醛 以 乙醚 为溶剂， 生成 tetrakis(salicylaldehydato)zirconium(IV)
  参考文献：
  名称：

  Chaudhry; Verma; Bhatt, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2008, vol. 47, # 1, p. 43 - 48

  摘要：

  DOI：

文献信息

• Archer, Ronald D.; Wang, Bing, Inorganic Chemistry, 1990, vol. 29, # 1, p. 39 - 43
  作者：Archer, Ronald D.、Wang, Bing

  DOI：——

  日期：——