[Cu(isatin aminoguanisone(1-))Cl] | 558452-76-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Cu(isatin aminoguanisone(1-))Cl]
• 英文别名: chlorocopper(1+);(3E)-3-(diaminomethylidenehydrazinylidene)indol-2-olate
• CAS: 558452-76-9
• 化学式: C₉H₈ClCuN₅O
• 分子量: 301.194
• InChiKey: JAKHPUIMEQPFMU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.25
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 (2Z)-2-(2-Oxo-1,2-dihydro-3H-indol-3-ylidene)hydrazinecarboximidamide 以 乙醇 为溶剂， 生成 [Cu(isatin aminoguanisone(1-))Cl]
  参考文献：
  名称：

  摘要：

  New complexes of bivalent Co, Ni, and Cu with isatin aminoguanisone (HL) and nitroaminoguanisone (HL1) of the composition ([Co(HL)(2)]Cl-2 (I), [Ni(HL)(2)]Cl-2 (II). [Cu(L)Cl] (III), [Co(L-1)(2)] (IV), [Ni(L-1)(2)] (V), and [Cu(L-1)(2)] (VI) are synthesized. Their molecular conductivities and effective magnetic moments are measured and thermal stabilities are studied. The type of the ligand coordination in I-VI is pro posed on the basis of IR data. The summary of physicochemical data for I-VI and the energy calculations for their molecules by the molecular mechanics method made it possible to establish stoichiometry of the coordination polyhedra of the complexes.

  DOI：

  10.1023/a:1026076117193