threo-1,9,10-octadecanetriol | 5058-06-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: threo-1,9,10-octadecanetriol
• 英文别名: (+/-)-threo-Octadecan-1,9,10-triol；(9SR,10SR)-octadecane-1,9,10-triol；(9RS,10RS)-octadecane-1,9,10-triol；(+/-)-threo-octadecane-1,9,10-triol；niedrigerschmelzendes Octadecantriol-(1,9,10)；Elaidicerin；rel-(9R,10R)-1,9,10-Octadecanetriol；(9R,10R)-octadecane-1,9,10-triol
• CAS: 5058-06-0
• 化学式: C₁₈H₃₈O₃
• 分子量: 302.498
• InChiKey: RGQVEMVVEFTMJD-QZTJIDSGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.18
• 重原子数：
  21.0
• 可旋转键数：
  16.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.69
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  threo-1,9,10-octadecanetriol 在 lead(IV) acetate 、 溶剂黄146 作用下， 生成 9-hydroxynonanal
  参考文献：
  名称：

  Scanlan; Swern, Journal of the American Chemical Society, 1940, vol. 62, p. 2307

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-9,10-epoxystearic acid 在 lithium aluminium tetrahydride 作用下， 生成 threo-1,9,10-octadecanetriol
  参考文献：
  名称：

  874.脂肪族酸。第二部分 一些脂族环氧酸及相关化合物

  摘要：

  DOI：

  10.1039/jr9600004514

文献信息

• Hot water as a mild Brønsted acid catalyst in ring opening reactions of epoxides
  作者：ZhaoBing Xu、Jin Qu

  DOI：10.1007/s11426-011-4323-x

  日期：2011.11

  Ring opening of extremely hydrophobic epoxides with water, amines, sodium azide and thiophenol was realized in the mixture solvent of water and 1, 4-dioxane under reflux condition. Hot water was believed to act as a mild Brønsted acid catalyst in the epoxide-opening reactions.

  在水和 1，4-二氧六环的混合溶剂中，在回流条件下实现了疏水性极强的环氧化物与水、胺、叠氮化钠和苯硫酚的开环反应。在环氧化物开环反应中，热水被认为是一种温和的布氏酸催化剂。
• Synthesis and characterization of single-chain second generation cleavable surfactants
  作者：David A. Jaeger、Yasmin M. Sayed

  DOI：10.1021/jo00061a044

  日期：1993.4

  Three series of single-chain, second generation cleavable surfactants, trans- [8- (2,2-dialkyl-5-octyl-1,3-dioxolan-4-yl)octyl]trimethylammonium methanesulfonate (1) and sodium (2) and triethanolammonium trans-8-(2,2-dialkyl-5-octyl-1,3-dioxolan-4-yl)octane-1-sulfate (3) (a, R = Me; b, R = Et; c, R = Pr; d, R = Bu), were prepared. They were characterized by critical micelle concentration, Krafft temperature, and dynamic laser light scattering measurements. Acid-catalyzed hydrolysis of surfactants 1, 2, and 3 gives (threo-9,10-dihydroxyoctadecyl)trimethylammonium methanesulfonate (4) and sodium (6) and triethanolammonium threo-9,10-dihydroxyoctadecane-1-sulfate (7), respectively, and a dialkyl ketone 5 (a, Me2CO; b, Et2CO; c, Pr2CO; d, Bu2CO). Cleavage of these surfactants thus gives another surfactant, with a higher critical micelle concentration, and a water-soluble neutral compound. Surfactants 3 were about 20 times more reactive than 1.
• Polyhydric alcohol esters
  申请人：DU PONT

  公开号：US02062918A1

  公开（公告）日：1936-12-01
• 88. Fatty acids. Part V. Applications of the Woodward cis-hydroxylation procedure to long-chain olefinic compounds
  作者：F. D. Gunstone、L. J. Morris

  DOI：10.1039/jr9570000487

  日期：——
• Andre; Francois, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1927, vol. 185, p. 388
  作者：Andre、Francois

  DOI：——

  日期：——