dysprosium phthalocyanine acetate | 164168-95-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: dysprosium phthalocyanine acetate
• CAS: 164168-95-0
• 化学式: C₃₄H₁₉DyN₈O₂
• 分子量: 734.077
• InChiKey: FTLDCFXMLVRNPW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dysprosium phthalocyanine acetate 在 溶剂黄146 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 生成 酞青
  参考文献：
  名称：

  Mutual Influence of Ligands and Reactivity of Gd and Dy Acidophthalocyaninate Complexes

  摘要：

  The results of the kinetic study of dissociation of Gd(III) and Dy(III) complexes with phthalocyanine of the composition (X)LnPc (X is single-charged acido ligand) with isolation of macrocyclic ligand depending on the temperature, composition of mixed ethanol-acetic acid solvent, and the nature of acido ligand are presented. The total kinetic equations, the rate constants, and activation parameters of dissociation reaction are determined. The stoichiomeric mechanism is suggested for the complex dissociation involving the limiting elementary reaction between acetic acid molecule and the complex that occurs as the chelate salt (X)LnPc or the outer-sphere complex [(HOAc)LnPc]X-+(-). The state of metal phthalocyaninate at the reaction slow stage is shown to be determined by the electronic structure of the metal cation, the strength of binding of the axial ligand, and by its cis-effect on the metal bonds with macrocycle.

  DOI：

  10.1023/b:ruco.0000040727.21739.44
• 作为产物：
  描述：

  dilitium phthalocyanine 、 dysprosium(III) acetate 在 水 作用下， 以 水 、 二甲基亚砜 为溶剂， 生成 dysprosium phthalocyanine acetate
  参考文献：
  名称：

  Mutual Influence of Ligands and Reactivity of Gd and Dy Acidophthalocyaninate Complexes

  摘要：

  The results of the kinetic study of dissociation of Gd(III) and Dy(III) complexes with phthalocyanine of the composition (X)LnPc (X is single-charged acido ligand) with isolation of macrocyclic ligand depending on the temperature, composition of mixed ethanol-acetic acid solvent, and the nature of acido ligand are presented. The total kinetic equations, the rate constants, and activation parameters of dissociation reaction are determined. The stoichiomeric mechanism is suggested for the complex dissociation involving the limiting elementary reaction between acetic acid molecule and the complex that occurs as the chelate salt (X)LnPc or the outer-sphere complex [(HOAc)LnPc]X-+(-). The state of metal phthalocyaninate at the reaction slow stage is shown to be determined by the electronic structure of the metal cation, the strength of binding of the axial ligand, and by its cis-effect on the metal bonds with macrocycle.

  DOI：

  10.1023/b:ruco.0000040727.21739.44

文献信息

• Phthalocyanine-polyoxotungstate lanthanide double deckers
  作者：Sidra Sarwar、Sergio Sanz、Jan van Leusen、Gary S. Nichol、Euan K. Brechin、Paul Kögerler

  DOI：10.1039/d0dt03716h

  日期：——

  Two archetypal tetradentate ligands with square donor patterns, namely phthalocyanate and monolacunary Keggin-type polyoxotungstate, coordinate to rare earth ions to yield C_s-symmetric heteroleptic double-decker complexes.

  两种具有方形供体模式的典型四价配体（即酞菁酸盐和单性凯金型多氧钨酸盐）与稀土离子配位，生成铯对称异极双层复合物。
• Synthesis and characterization of some lanthanide phthalocyanines
  作者：G. Clarisse、M.T. Riou

  DOI：10.1016/s0020-1693(00)85943-5

  日期：1987.6
• Lomova, T. N.; Andrianova, L. G., Russian Journal of Inorganic Chemistry, 1994, vol. 39, p. 1926 - 1931
  作者：Lomova, T. N.、Andrianova, L. G.

  DOI：——

  日期：——