Tri-isopropylantimondibromid | 58037-61-9

• 分子结构分类: 有机化合物
• 英文名称: Tri-isopropylantimondibromid
• 英文别名: Tri-isobutyl-antimondibromid；(i-C3H7)3SbBr2；Pr(i)3SbBr2；dibromo-tri(propan-2-yl)-λ5-stibane
• CAS: 58037-61-9
• 化学式: C₉H₂₁Br₂Sb
• 分子量: 410.824
• InChiKey: ZKRPKNPUVHVEGM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Tri-isopropylantimondibromid 以 异丙醇 、 苯 为溶剂， 生成 triisopropylantimony(V) 2-picolinate
  参考文献：
  名称：

  Triorganoantimony(V) carboxylates: Synthesis, characterization and crystal structure of [Me3Sb(O2C–C5H4N)2]·H2O

  摘要：

  Reactions of [R3Sb(OPri)(2)] with N-heterocylic carboxylic acids gave compounds of the type [R3Sb(O2C-Ar)(2)] (1) (R = Me, Et, Pr-i, Ph; Ar = 2-C5H4N, 2-C9H6N). The mono-bromo compound [Me3Sb(Br)(O2C-C5H4N)] (2) exists in equilibrium with [Me3Sb(O2C-C5H4N)(2)] and [Me3SbBr2]. All new compounds have been characterized by IR and NMR (H-1 and C-13{H-1}) spectral data. X-ray structural analysis of one example, [Me3Sb(O2C-C5H4N)(2)], isolated as its monohydrate, revealed an essentially trigonal bipyramidal geometry for the antimony atom defined by three equilaterally disposed methyl groups and two oxygen atoms from monodentate carboxylate groups, in apical positions. The crystal structure is consolidated into a three-dimensional network by cooperative O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot O interactions. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.033
• 作为产物：
  描述：

  triisopropylantimony 在 溴 作用下， 生成 Tri-isopropylantimondibromid
  参考文献：
  名称：

  Vibrational study of triethyl- and triisopropylantimony dihalides.

  摘要：

  DOI：

  10.1016/0584-8539(75)80113-9

文献信息

• Triorganoantimony(V) complexes with internally functionallized oximes: synthetic, spectroscopic and structural aspects of [R3Sb(Br)L], [R3Sb(OH)L] and [R3SbL2], crystal and molecular structures of [Me3Sb{ONC(Me)C4H3O}2], [Me3Sb{ONC(Me)C4H3S}2], 2-OC4H3C(Me)NOH and 2-SC4H3C(Me)NOH
  作者：Anjali Gupta、Rajnish K Sharma、Rakesh Bohra、Vimal K Jain、John E Drake、Michael B Hursthouse、Mark E Light

  DOI：10.1016/s0022-328x(01)01338-9

  日期：2002.2

  hydrolysis of 1 (R=Pri; Ar=C5H4N). All of these complexes have been characterized by elemental analyses, and IR and NMR (1H and 13C) spectroscopic studies. Crystal structures of [Me3SbONC(Me)C4H3O-2}2] (3), [Me3SbONC(Me)C4H3S-2}2] (4) 2-OC4H3C(Me)NOH (5) and 2-SC4H3C(Me)NOH (6) are reported. The geometry around the antimony atom in 3 and 4 is distorted trigonal bipyramidal with the carbon atoms of

  具有内部功能化的[R 3 Sb ONC（Me）Ar} 2 ]型肟的三有机锑（V）络合物（1）[R = Me，Pr i ; Ar ＝ C 5 H 4 N，C 4 H 3 S，C 4 H 3 O]是通过R 3 SbBr 2与相应的肟在无水苯中以1：2的摩尔比反应制备的。用一当量的R 3 SbX 2处理1得到重分布产物[R 3 Sb（X）ONC（Me）Ar}]（2）[X =（a）：Br，（b）：OH]。还可以通过控制水解1（R = Pr i ; Ar = C 5 H 4 N）来获得R 3 Sb（OH）L 。所有这些络合物均已通过元素分析，IR和NMR（1 H和13 C）光谱研究进行了表征。[Me 3 Sb ONC（Me）C 4 H 3 O-2} 2 ]（3），[Me 3 Sb ONC（Me）C 4 H 3 S-2} 2 ]的晶体结构（4）2-OC 4 H 3 C（Me）NOH（报道了5）和2-SC
• Hartmann, H.; Kuehl, G., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Hartmann, H.、Kuehl, G.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.2, 1.2.1.1.5.1, page 20 - 24
  作者：

  DOI：——

  日期：——
• Breunig, H. J.; Kanig, W., Phosphorus and Sulfur and the Related Elements, 1981, vol. 12, p. 149 - 160
  作者：Breunig, H. J.、Kanig, W.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.1.4, page 25 - 25
  作者：

  DOI：——

  日期：——